JEE Challenger
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Total Number of Cyclic Isomers for C4H6 Hydrocarbon

The total number of cyclic isomers possible for a hydrocarbon with the molecular formula C4H6\text{C}_4\text{H}_6 is

Official Numerical Answer5

Step-by-Step Solution

To find the total number of cyclic isomers for a hydrocarbon with the molecular formula C4H6\text{C}_4\text{H}_6, we first calculate its Degree of Unsaturation (DU\text{DU}) or Index of Hydrogen Deficiency (IHD\text{IHD}):

DU=C+1−H2=4+1−62=5−3=2\text{DU} = C + 1 - \frac{H}{2} = 4 + 1 - \frac{6}{2} = 5 - 3 = 2

Since we are looking for cyclic isomers, each isomer must contain at least one ring (DU≥1\text{DU} \ge 1). The remaining unsaturation (DU=1\text{DU} = 1) can be present as either:

  1. A double bond (monocyclic alkene / exocyclic double bond)
  2. A second ring (bicyclic alkane)

1. Four-membered ring isomers (Monocyclic with a double bond):

  • Cyclobutene

2. Three-membered ring isomers (Monocyclic with an endocyclic double bond):

  • 1-Methylcyclopropene
  • 3-Methylcyclopropene

3. Three-membered ring isomers (Monocyclic with an exocyclic double bond):

  • Methylenecyclopropane

4. Bicyclic isomers (Two fused rings):

  • Bicyclo[1.1.0]butane

Summary of Isomers:

  1. Cyclobutene
  2. 1-Methylcyclopropene
  3. 3-Methylcyclopropene
  4. Methylenecyclopropane
  5. Bicyclo[1.1.0]butane

None of these structures exhibit stereoisomerism (optical or geometrical isomerism).

Therefore, the total number of cyclic isomers for C4H6\text{C}_4\text{H}_6 is 5.