JEE Challenger
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Thermodynamic Cyclic Process of Ideal Gas on Volume-Temperature Diagram

One mole of an ideal gas in initial state A undergoes a cyclic process ABCA, as shown in the figure. Its pressure at A is P0\text{P}_0. Choose the correct option(s) from the following

Diagram 0

Options

A

Internal energies at A and B are the same

Correct
B

Work done by the gas in process AB is P0V0ln⁡4\text{P}_0\text{V}_0 \ln 4

Correct
C

Pressure at C is P04\frac{\text{P}_0}{4}

Correct
D

Temperature at C is T04\frac{\text{T}_0}{4}

Correct

Step-by-Step Solution

To determine the correct option(s), we analyze the cyclic process ABCAABCA on the given V−TV-T diagram for n=1 molen = 1\text{ mole} of an ideal gas.

1. Analysis of States and Processes

  • State A:
    The temperature and volume at state A are TA=T0T_A = T_0 and VA=V0V_A = V_0.
    From the ideal gas equation (PV=nRTPV = nRT), the pressure at A is given by:
    P0=RT0V0  ⟹  P0V0=RT0P_0 = \frac{RT_0}{V_0} \implies P_0 V_0 = RT_0

  • Process AB:
    The path ABAB is a vertical line at constant temperature T=T0T = T_0.
    Thus, TB=T0T_B = T_0 and VB=4V0V_B = 4V_0. Process ABAB is an isothermal expansion.

  • Process BC:
    The path BCBC lies on a straight line passing through the origin (0,0)(0, 0) and point B (T0,4V0)(T_0, 4V_0).

  • Process CA:
    The path CACA is a horizontal line at constant volume V=V0V = V_0. Thus, VC=V0V_C = V_0.


2. Verification of Options

  • Option A: Internal energies at A and B are the same

    The internal energy of an ideal gas depends only on its temperature:
    U=nCvTU = n C_v T
    Since TA=TB=T0T_A = T_B = T_0, we have UA=UBU_A = U_B.

    Option A is correct.

  • Option B: Work done by the gas in process AB is P0V0ln⁡4P_0 V_0 \ln 4

    Since process ABAB is isothermal at temperature T0T_0, the work done by the gas is:
    WAB=nRT0ln⁡(VBVA)W_{AB} = n R T_0 \ln\left(\frac{V_B}{V_A}\right)
    Substituting n=1n = 1, VA=V0V_A = V_0, and VB=4V0V_B = 4V_0:
    WAB=1⋅RT0ln⁡(4V0V0)=RT0ln⁡4W_{AB} = 1 \cdot R T_0 \ln\left(\frac{4V_0}{V_0}\right) = RT_0 \ln 4
    Since RT0=P0V0RT_0 = P_0 V_0:
    WAB=P0V0ln⁡4W_{AB} = P_0 V_0 \ln 4

    Option B is correct.

  • Option D: Temperature at C is T04\frac{T_0}{4}

    Since the line BCBC passes through the origin in the V−TV-T plane, its relation is given by V=kTV = kT, where kk is a constant slope.
    Using state B (T0,4V0)(T_0, 4V_0):
    k=VBTB=4V0T0k = \frac{V_B}{T_B} = \frac{4V_0}{T_0}
    For state C (TC,V0)(T_C, V_0):
    VC=kTC  ⟹  V0=(4V0T0)TC  ⟹  TC=T04V_C = k T_C \implies V_0 = \left(\frac{4V_0}{T_0}\right) T_C \implies T_C = \frac{T_0}{4}

    Option D is correct.

  • Option C: Pressure at C is P04\frac{P_0}{4}

    For process BCBC, since V∝TV \propto T, the ratio VT\frac{V}{T} is constant.
    From the ideal gas equation P=RTVP = \frac{RT}{V}, a constant ratio of VT\frac{V}{T} implies that pressure PP remains constant along line BCBC (an isobaric process).
    Therefore, PC=PBP_C = P_B.
    The pressure at state B is:
    PB=RTBVB=RT04V0=P04P_B = \frac{RT_B}{V_B} = \frac{RT_0}{4V_0} = \frac{P_0}{4}
    Hence, PC=P04P_C = \frac{P_0}{4}.

    Option C is correct.


Conclusion

All options A, B, C, and D are correct.