JEE Challenger
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Identification of Heat Absorption Steps in Four Step Gas Cycle

An ideal gas is taken through a four-step cyclic process as shown in the P−VP - V diagram below. Identify the steps in which heat is absorbed by the gas.

Question Diagram 1

Options

A

steps 1 and 2

B

steps 1 and 3

C

steps 1 and 4

Correct
D

steps 2 and 4

Step-by-Step Solution

To determine the steps in which heat is absorbed by the ideal gas, we use the First Law of Thermodynamics: Q=ΔU+WQ = \Delta U + W where:

  • QQ is the heat added to the system,
  • ΔU=nCvΔT\Delta U = n C_v \Delta T is the change in internal energy,
  • W=∫P dVW = \int P \, dV is the work done by the gas.

From the ideal gas law PV=nRTPV = nRT, the temperature TT is directly proportional to the product PVPV.


Analysis of Each Step:

  1. Step 1: Isobaric Expansion

    • Pressure (PP): Constant at a higher value PhighP_{\text{high}}
    • Volume (VV): Increases (ΔV>0\Delta V > 0), so the work done is positive: W1=PhighΔV>0W_1 = P_{\text{high}} \Delta V > 0.
    • Temperature (TT): Since PP is constant and VV increases, T=PVnRT = \frac{PV}{nR} increases (ΔT>0\Delta T > 0).
    • Internal Energy (ΔU\Delta U): ΔU1=nCvΔT>0\Delta U_1 = n C_v \Delta T > 0.
    • Heat (QQ): Q1=ΔU1+W1>0Q_1 = \Delta U_1 + W_1 > 0
    • Thus, heat is absorbed in step 1.
  2. Step 2: Isochoric Pressure Drop

    • Volume (VV): Constant at VhighV_{\text{high}} (ΔV=0  ⟹  W2=0\Delta V = 0 \implies W_2 = 0).
    • Pressure (PP): Decreases (ΔP<0\Delta P < 0).
    • Temperature (TT): Since VV is constant and PP decreases, TT decreases (ΔT<0\Delta T < 0).
    • Internal Energy (ΔU\Delta U): ΔU2=nCvΔT<0\Delta U_2 = n C_v \Delta T < 0.
    • Heat (QQ): Q2=ΔU2+0<0Q_2 = \Delta U_2 + 0 < 0
    • Thus, heat is released in step 2.
  3. Step 3: Isobaric Compression

    • Pressure (PP): Constant at a lower value PlowP_{\text{low}}
    • Volume (VV): Decreases (ΔV<0\Delta V < 0), so W3=PlowΔV<0W_3 = P_{\text{low}} \Delta V < 0.
    • Temperature (TT): Since PP is constant and VV decreases, TT decreases (ΔT<0\Delta T < 0).
    • Internal Energy (ΔU\Delta U): ΔU3=nCvΔT<0\Delta U_3 = n C_v \Delta T < 0.
    • Heat (QQ): Q3=ΔU3+W3<0Q_3 = \Delta U_3 + W_3 < 0
    • Thus, heat is released in step 3.
  4. Step 4: Isochoric Pressure Increase

    • Volume (VV): Constant at VlowV_{\text{low}} (ΔV=0  ⟹  W4=0\Delta V = 0 \implies W_4 = 0).
    • Pressure (PP): Increases (ΔP>0\Delta P > 0).
    • Temperature (TT): Since VV is constant and PP increases, TT increases (ΔT>0\Delta T > 0).
    • Internal Energy (ΔU\Delta U): ΔU4=nCvΔT>0\Delta U_4 = n C_v \Delta T > 0.
    • Heat (QQ): Q4=ΔU4+0>0Q_4 = \Delta U_4 + 0 > 0
    • Thus, heat is absorbed in step 4.

Conclusion:

Heat is absorbed by the gas in steps 1 and 4.

Correct Option: (C)