JEE Challenger
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Heat Required for Expandable Balloon Containing Helium Gas

A rubber balloon contains two moles of ideal helium gas at 30∘C30^\circ\text{C}. The balloon is fully expandable and requires no energy for its expansion. The temperature of the gas inside the balloon is slowly raised to 35∘C35^\circ\text{C}. Find the approximate amount of heat required to increase the temperature (take R=8.31 J/mol⋅KR = 8.31\ \text{J/mol}\cdot\text{K}).

Options

A

62 J62\ \text{J}

B

104 J104\ \text{J}

C

124 J124\ \text{J}

D

208 J208\ \text{J}

Correct

Step-by-Step Solution

To find the heat required to raise the temperature of the helium gas inside the balloon, we analyze the thermodynamic process taking place:

1. Identify the Gas Properties

  • Helium is a monoatomic ideal gas.
  • For a monoatomic ideal gas, the molar heat capacity at constant volume (CvC_v) and constant pressure (CpC_p) are given by: Cv=32RC_v = \frac{3}{2}R Cp=Cv+R=52RC_p = C_v + R = \frac{5}{2}R

2. Identify the Nature of the Process

  • The balloon is fully expandable and requires no energy for its elastic expansion.
  • As a result, the pressure inside the balloon remains equal to the constant external atmospheric pressure (P=constantP = \text{constant}).
  • Therefore, the heating process occurs at constant pressure (an isobaric process).

3. Calculate the Heat Required (QQ)

The heat required at constant pressure is given by: Q=nCpΔTQ = n C_p \Delta T

Given data:

  • Number of moles, n=2 moln = 2\text{ mol}
  • Universal gas constant, R=8.31 J/(mol⋅K)R = 8.31\text{ J/(mol}\cdot\text{K)}
  • Temperature change, ΔT=35∘C−30∘C=5 K\Delta T = 35^\circ\text{C} - 30^\circ\text{C} = 5\text{ K}

Substituting the value of Cp=52RC_p = \frac{5}{2}R: Q=n(52R)ΔTQ = n \left(\frac{5}{2} R\right) \Delta T

Q=2×52×8.31×5Q = 2 \times \frac{5}{2} \times 8.31 \times 5

Q=25×8.31 J=207.75 J≈208 JQ = 25 \times 8.31\text{ J} = 207.75\text{ J} \approx 208\text{ J}

Thus, the approximate amount of heat required is 208 J208\text{ J}.

Correct Option: D