JEE Challenger
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Adiabatic Compression of Monatomic and Diatomic Gas Mixture

Consider a mixture of ideal gases comprising 5 moles5\text{ moles} of a monatomic gas and 1 mole1\text{ mole} of a rigid diatomic gas, initially at pressure P0P_0, volume V0V_0, and temperature T0T_0. If the gas mixture is compressed adiabatically to a volume V0/4V_0/4, choose the correct statement(s): (Given 21.2=2.32^{1.2} = 2.3; 23.2=9.22^{3.2} = 9.2; RR is the gas constant)

Options

A

The magnitude of work ∣W∣|W| performed during the process is 13RT013 R T_0

Correct
B

The average kinetic energy of the gas mixture post compression lies between 18RT018 R T_0 and 19RT019 R T_0

C

The final pressure of the mixture following compression lies between 9P09 P_0 and 10P010 P_0

Correct
D

The adiabatic index of the gas mixture equals 1.61.6

Correct

Step-by-Step Solution

To evaluate the correct options for the adiabatic compression of the gas mixture, we calculate the effective molar specific heat capacity at constant volume and the adiabatic index, then apply the adiabatic state equations to determine the final pressure, temperature, and work done.

First, the total molar heat capacity at constant volume CVC_V for the mixture of n1=5 molesn_1 = 5\text{ moles} of monatomic gas (CV1=32RC_{V1} = \frac{3}{2}R) and n2=1 molen_2 = 1\text{ mole} of rigid diatomic gas (CV2=52RC_{V2} = \frac{5}{2}R) is: CV=n1CV1+n2CV2n1+n2=5(32R)+1(52R)5+1=53RC_V = \frac{n_1 C_{V1} + n_2 C_{V2}}{n_1 + n_2} = \frac{5\left(\frac{3}{2}R\right) + 1\left(\frac{5}{2}R\right)}{5 + 1} = \frac{5}{3}R

The adiabatic index γ\gamma of the mixture is: γ=1+RCV=1+35=1.6\gamma = 1 + \frac{R}{C_V} = 1 + \frac{3}{5} = 1.6 This matches statement (D).

For an adiabatic process, PVγ=constantP V^\gamma = \text{constant}. The final pressure PfP_f after compressing to Vf=V0/4V_f = V_0/4 is: Pf=P0(V0Vf)γ=P0(4)1.6=P0⋅23.2=9.2P0P_f = P_0 \left(\frac{V_0}{V_f}\right)^\gamma = P_0 (4)^{1.6} = P_0 \cdot 2^{3.2} = 9.2 P_0 Since 9P0<9.2P0<10P09 P_0 < 9.2 P_0 < 10 P_0, statement (C) is correct.

The final temperature TfT_f is given by TVγ−1=constantT V^{\gamma-1} = \text{constant}: Tf=T0(V0Vf)γ−1=T0(4)0.6=T0⋅21.2=2.3T0T_f = T_0 \left(\frac{V_0}{V_f}\right)^{\gamma-1} = T_0 (4)^{0.6} = T_0 \cdot 2^{1.2} = 2.3 T_0

The magnitude of work done during the adiabatic process is: ∣W∣=∣ΔU∣=(n1+n2)CV(Tf−T0)=6⋅(53R)(2.3T0−T0)=10R(1.3T0)=13RT0|W| = |\Delta U| = (n_1 + n_2) C_V (T_f - T_0) = 6 \cdot \left(\frac{5}{3}R\right) (2.3 T_0 - T_0) = 10 R (1.3 T_0) = 13 R T_0 This matches statement (A).

The total translational and rotational kinetic energy of the mixture post-compression is: Ek=(n1+n2)CVTf=6⋅(53R)(2.3T0)=23RT0E_k = (n_1 + n_2) C_V T_f = 6 \cdot \left(\frac{5}{3}R\right) (2.3 T_0) = 23 R T_0 Thus, statement (B) is incorrect.

Hence, the correct options are (A), (C), and (D).