JEE Challenger
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Ratio of Isothermal to Adiabatic Work for Expansion of Helium Gas

An ideal gas consisting of one mole of helium is enclosed in a vessel with initial pressure P1P_1 and volume V1V_1. First, it undergoes isothermal expansion to a volume of 4V14V_1. Subsequently, it undergoes adiabatic expansion until the volume reaches 32V132V_1. Let WisoW_{\text{iso}} and WadiaW_{\text{adia}} denote the work done during the isothermal and adiabatic stages, respectively. If the ratio WisoWadia=fln⁡2\frac{W_{\text{iso}}}{W_{\text{adia}}} = f \ln 2, then the value of ff is equal to __________.

Official Numerical Answer1.78

Step-by-Step Solution

To find the value of ff, we analyze the work done during each of the two thermodynamic stages for one mole (n=1n = 1) of helium gas.

1. Properties of Helium Gas

Helium is a monoatomic ideal gas, which has 33 degrees of freedom. Therefore, its adiabatic index γ\gamma is given by: γ=1+23=53\gamma = 1 + \frac{2}{3} = \frac{5}{3}

Let the initial state of the gas be (P1,V1,T1)(P_1, V_1, T_1).


2. Isothermal Expansion Stage

During the first stage, the gas undergoes an isothermal expansion at temperature T1T_1 from volume V1V_1 to volume V2=4V1V_2 = 4V_1.

The work done during this isothermal process, WisoW_{\text{iso}}, is: Wiso=nRT1ln⁡(V2V1)W_{\text{iso}} = n R T_1 \ln\left(\frac{V_2}{V_1}\right)

Substituting n=1n = 1 and V2=4V1V_2 = 4V_1: Wiso=RT1ln⁡(4V1V1)=RT1ln⁡(4)=2RT1ln⁡2W_{\text{iso}} = R T_1 \ln\left(\frac{4V_1}{V_1}\right) = R T_1 \ln(4) = 2 R T_1 \ln 2

At the end of this stage, the temperature of the gas remains T2=T1T_2 = T_1, and its volume is V2=4V1V_2 = 4V_1.


3. Adiabatic Expansion Stage

During the second stage, the gas expands adiabatically from volume V2=4V1V_2 = 4V_1 to V3=32V1V_3 = 32V_1.

Using the relation TVγ−1=constantT V^{\gamma - 1} = \text{constant} for an adiabatic process: T2V2γ−1=T3V3γ−1T_2 V_2^{\gamma - 1} = T_3 V_3^{\gamma - 1}

Substituting T2=T1T_2 = T_1, V2=4V1V_2 = 4V_1, V3=32V1V_3 = 32V_1, and γ=53\gamma = \frac{5}{3}: T1(4V1)53−1=T3(32V1)53−1T_1 (4V_1)^{\frac{5}{3} - 1} = T_3 (32V_1)^{\frac{5}{3} - 1} T3=T1(4V132V1)2/3=T1(18)2/3T_3 = T_1 \left(\frac{4V_1}{32V_1}\right)^{2/3} = T_1 \left(\frac{1}{8}\right)^{2/3}

Since (18)2/3=(2−3)2/3=2−2=14\left(\frac{1}{8}\right)^{2/3} = (2^{-3})^{2/3} = 2^{-2} = \frac{1}{4}, the final temperature T3T_3 is: T3=T14T_3 = \frac{T_1}{4}

The work done during the adiabatic process, WadiaW_{\text{adia}}, is given by: Wadia=nR(T2−T3)γ−1W_{\text{adia}} = \frac{n R (T_2 - T_3)}{\gamma - 1}

Substituting n=1n = 1, T2=T1T_2 = T_1, T3=T14T_3 = \frac{T_1}{4}, and γ−1=23\gamma - 1 = \frac{2}{3}: Wadia=R(T1−T14)23=R⋅34T123=98RT1W_{\text{adia}} = \frac{R \left(T_1 - \frac{T_1}{4}\right)}{\frac{2}{3}} = \frac{R \cdot \frac{3}{4} T_1}{\frac{2}{3}} = \frac{9}{8} R T_1


4. Calculation of the Ratio WisoWadia\frac{W_{\text{iso}}}{W_{\text{adia}}}

Taking the ratio of WisoW_{\text{iso}} to WadiaW_{\text{adia}}: WisoWadia=2RT1ln⁡298RT1=298ln⁡2=169ln⁡2\frac{W_{\text{iso}}}{W_{\text{adia}}} = \frac{2 R T_1 \ln 2}{\frac{9}{8} R T_1} = \frac{2}{\frac{9}{8}} \ln 2 = \frac{16}{9} \ln 2

Given that WisoWadia=fln⁡2\frac{W_{\text{iso}}}{W_{\text{adia}}} = f \ln 2, we get: f=169≈1.78f = \frac{16}{9} \approx 1.78