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Proportionality of Discrete Particle Speed with Quantum Number

The speed of the particle, that can take discrete values, is proportional to

Options

A

n−3/2n^{-3/2}

B

n−1n^{-1}

C

n1/2n^{1/2}

D

nn

Correct

Topics & Concepts

Step-by-Step Solution

Based on the quantum mechanical description of a particle of mass mm confined within a one-dimensional region of width aa (an infinite potential well):

  1. Quantization Condition:
    The standing wave condition for the de Broglie wavelength λn\lambda_n of the particle in a box of width aa is given by:
    nλn2=a  ⟹  λn=2an,for n=1,2,3,…n \frac{\lambda_n}{2} = a \implies \lambda_n = \frac{2a}{n}, \quad \text{for } n = 1, 2, 3, \ldots

  2. Momentum and Speed of the Particle:
    Using the de Broglie relation pn=hλnp_n = \frac{h}{\lambda_n}, the momentum of the particle in the nn-th state is:
    pn=nh2ap_n = \frac{n h}{2a}

    Since the magnitude of momentum is related to the speed vnv_n of the particle by pn=mvnp_n = m v_n, we obtain:
    mvn=nh2a  ⟹  vn=nh2mam v_n = \frac{n h}{2a} \implies v_n = \frac{n h}{2 m a}

  3. Proportionality:
    Since hh, mm, and aa are constants:
    vn∝nv_n \propto n

Therefore, the speed of the particle is proportional to nn.

Correct Option: D