Number of Atoms in Hexagonal Close Packed Unit Cell
In hexagonal systems of crystals, a frequently encountered arrangement of atoms is described as a hexagonal prism. Here, the top and bottom of the cell are regular hexagons and three atoms are sandwiched in between them. A space-filling model of this structure, called hexagonal close-packed (HCP), is constituted of a sphere on a flat surface surrounded in the same plane by six identical spheres as closely as possible. Three spheres are then placed over the first layer so that they touch each other and represent the second layer. Each one of these three spheres touches three spheres of the bottom layer. Finally, the second layer is covered with a third layer that is identical to the bottom layer in relative position. Assume radius of every sphere to be ''.
The number of atoms in this HCP unit cell is
Options
4
6
12
17
Topics & Concepts
Step-by-Step Solution
To determine the effective number of atoms () in a hexagonal close-packed () unit cell:
-
Corner atoms:
The unit cell is a hexagonal prism which has corners ( on the top base and on the bottom base). Each corner atom is shared equally among neighboring unit cells.
-
Face-centered atoms:
There are atoms situated at the centers of the hexagonal faces ( on the top face and on the bottom face). Each face-centered atom is shared between adjacent unit cells.
-
Body atoms:
There are atoms completely contained within the interior of the unit cell (the intermediate layer sandwiched between the top and bottom hexagonal layers).
Summing the contributions:
Thus, the number of atoms in this unit cell is .
Correct Option: (B)