JEE Challenger
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Number of Atoms in Hexagonal Close Packed Unit Cell

Comprehension Passage

In hexagonal systems of crystals, a frequently encountered arrangement of atoms is described as a hexagonal prism. Here, the top and bottom of the cell are regular hexagons and three atoms are sandwiched in between them. A space-filling model of this structure, called hexagonal close-packed (HCP), is constituted of a sphere on a flat surface surrounded in the same plane by six identical spheres as closely as possible. Three spheres are then placed over the first layer so that they touch each other and represent the second layer. Each one of these three spheres touches three spheres of the bottom layer. Finally, the second layer is covered with a third layer that is identical to the bottom layer in relative position. Assume radius of every sphere to be 'rr'.

The number of atoms in this HCP unit cell is

Options

A

4

B

6

Correct
C

12

D

17

Topics & Concepts

Step-by-Step Solution

To determine the effective number of atoms (ZZ) in a hexagonal close-packed (HCP\text{HCP}) unit cell:

  1. Corner atoms:
    The unit cell is a hexagonal prism which has 1212 corners (66 on the top base and 66 on the bottom base). Each corner atom is shared equally among 66 neighboring unit cells.
    Contribution from corners=12×16=2\text{Contribution from corners} = 12 \times \frac{1}{6} = 2

  2. Face-centered atoms:
    There are 22 atoms situated at the centers of the hexagonal faces (11 on the top face and 11 on the bottom face). Each face-centered atom is shared between 22 adjacent unit cells.
    Contribution from face centers=2×12=1\text{Contribution from face centers} = 2 \times \frac{1}{2} = 1

  3. Body atoms:
    There are 33 atoms completely contained within the interior of the unit cell (the intermediate layer sandwiched between the top and bottom hexagonal layers).
    Contribution from the interior=3×1=3\text{Contribution from the interior} = 3 \times 1 = 3

Summing the contributions:
Z=2+1+3=6Z = 2 + 1 + 3 = 6

Thus, the number of atoms in this HCP\text{HCP} unit cell is 66.

Correct Option: (B)