Identify Common Metals Occurring as Sulfide Ores
Sulfide ores are commonly found for which group of metals?
Options
ACorrect
, and
B
, and
C
, and
D
, and
Topics & Concepts
Step-by-Step Solution
To determine which group of metals commonly occurs in nature as sulfide ores, we analyze the principal ores and chemical characteristics of each given element:
-
Hard and Soft Acids and Bases (HSAB) Principle:
- The sulfide ion () is large and polarizable, behaving as a soft base.
- Highly electropositive metals with high charge density, such as and , are hard acids and strongly prefer hard bases like (oxides), (carbonates), or (fluorides). Therefore, and do not typically occur as sulfides.
- Less electropositive, more polarizable metal cations like , , , and are soft or borderline acids and have a strong affinity for sulfide ions (), thus readily forming stable sulfide minerals.
-
Common Ores of the Metals:
- Silver (): Commonly found as argentite or silver glance ().
- Copper (): Commonly found as copper pyrites or chalcopyrite (), copper glance or chalcocite (), and covellite ().
- Lead (): Commonly found as galena ().
- Tin (): Chiefly found as an oxide ore, cassiterite ().
- Magnesium (): Commonly found as carbonates and halides (e.g., magnesite , dolomite , carnallite ).
- Aluminium (): Commonly found as oxide/hydroxide ores (e.g., bauxite ) and fluorides (e.g., cryolite ).
From the above analysis:
- Options containing , , or are incorrect because their common ores are oxides, carbonates, or halides.
- The metals , , and all commonly occur as sulfide ores (, , and ).
Therefore, the correct option is (A).