JEE Challenger

Identify Common Metals Occurring as Sulfide Ores

Sulfide ores are commonly found for which group of metals?

Options

A

AgAg, CuCu and PbPb

Correct
B

AgAg, CuCu and SnSn

C

AgAg, MgMg and PbPb

D

AlAl, CuCu and PbPb

Step-by-Step Solution

To determine which group of metals commonly occurs in nature as sulfide ores, we analyze the principal ores and chemical characteristics of each given element:

  1. Hard and Soft Acids and Bases (HSAB) Principle:

    • The sulfide ion (S2−\text{S}^{2-}) is large and polarizable, behaving as a soft base.
    • Highly electropositive metals with high charge density, such as Al3+\text{Al}^{3+} and Mg2+\text{Mg}^{2+}, are hard acids and strongly prefer hard bases like O2−\text{O}^{2-} (oxides), CO32−\text{CO}_3^{2-} (carbonates), or F−\text{F}^{-} (fluorides). Therefore, Al\text{Al} and Mg\text{Mg} do not typically occur as sulfides.
    • Less electropositive, more polarizable metal cations like Ag+\text{Ag}^+, Cu+\text{Cu}^+, Cu2+\text{Cu}^{2+}, and Pb2+\text{Pb}^{2+} are soft or borderline acids and have a strong affinity for sulfide ions (S2−\text{S}^{2-}), thus readily forming stable sulfide minerals.
  2. Common Ores of the Metals:

    • Silver (Ag\text{Ag}): Commonly found as argentite or silver glance (Ag2S\text{Ag}_2\text{S}).
    • Copper (Cu\text{Cu}): Commonly found as copper pyrites or chalcopyrite (CuFeS2\text{CuFeS}_2), copper glance or chalcocite (Cu2S\text{Cu}_2\text{S}), and covellite (CuS\text{CuS}).
    • Lead (Pb\text{Pb}): Commonly found as galena (PbS\text{PbS}).
    • Tin (Sn\text{Sn}): Chiefly found as an oxide ore, cassiterite (SnO2\text{SnO}_2).
    • Magnesium (Mg\text{Mg}): Commonly found as carbonates and halides (e.g., magnesite MgCO3\text{MgCO}_3, dolomite CaCO3⋅MgCO3\text{CaCO}_3\cdot\text{MgCO}_3, carnallite KCl⋅MgCl2⋅6H2O\text{KCl}\cdot\text{MgCl}_2\cdot 6\text{H}_2\text{O}).
    • Aluminium (Al\text{Al}): Commonly found as oxide/hydroxide ores (e.g., bauxite AlOx(OH)3−2x\text{AlO}_x(\text{OH})_{3-2x}) and fluorides (e.g., cryolite Na3AlF6\text{Na}_3\text{AlF}_6).

From the above analysis:

  • Options containing Sn\text{Sn}, Mg\text{Mg}, or Al\text{Al} are incorrect because their common ores are oxides, carbonates, or halides.
  • The metals Ag\text{Ag}, Cu\text{Cu}, and Pb\text{Pb} all commonly occur as sulfide ores (Ag2S\text{Ag}_2\text{S}, CuFeS2/Cu2S\text{CuFeS}_2/\text{Cu}_2\text{S}, and PbS\text{PbS}).

Therefore, the correct option is (A).