JEE Challenger
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Calculate Radius of Cation in Octahedral Solid Lattice

The spatial arrangement of X−X^- ions surrounding an A+A^+ ion in a crystalline solid AXAX is shown in the figure (not drawn to scale). Given that the radius of the X−X^- ion is 250 pm250\text{ pm}, what is the radius of the A+A^+ ion?

Question Diagram 1

Options

A

104 pm104\text{ pm}

Correct
B

125 pm125\text{ pm}

C

183 pm183\text{ pm}

D

57 pm57\text{ pm}

Step-by-Step Solution

Based on the given figure, the A+A^+ ion is situated in an octahedral void surrounded by six X−X^- ions (coordination number = 66).

For a stable octahedral arrangement where the cation A+A^+ fits into the octahedral void formed by the anions X−X^-, the limiting radius ratio is given by: rA+rX−=2−1≈0.414\frac{r_{A^+}}{r_{X^-}} = \sqrt{2} - 1 \approx 0.414

Given: rX−=250 pmr_{X^-} = 250\text{ pm}

Substituting the value into the radius ratio relation: rA+=0.414×rX−r_{A^+} = 0.414 \times r_{X^-} rA+=0.414×250 pm=103.5 pm≈104 pmr_{A^+} = 0.414 \times 250\text{ pm} = 103.5\text{ pm} \approx 104\text{ pm}

Therefore, the radius of the A+A^+ ion is 104 pm104\text{ pm}, which corresponds to Option (A).