Determine Atomic Number from Successive Ionization Enthalpies
The , , and ionization enthalpies, and , of four elements having atomic numbers and , where , are provided in the table. Find the value of .
Step-by-Step Solution
To determine the atomic number , we analyze the trends and sudden jumps in the given ionization enthalpies ():
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Analyzing Element :
The large ratio indicates a massive jump between the first and second ionization energies. This signifies that the removal of the second electron involves removing an electron from a stable, fully filled noble gas shell. Therefore, the element with atomic number has valence electron and belongs to Group 1 (Alkali metals).
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Analyzing Element :
Here, the significant jump occurs between and (), which indicates that this element has valence electrons and belongs to Group 2 (Alkaline earth metals).
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Identifying the specific elements:
- The first ionization enthalpy of corresponds specifically to Sodium (), which has an atomic number .
- Consequently, the element with is Magnesium ().
- The elements and correspond to Fluorine (, ) and Neon (, ) respectively, which matches the high values of and .
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Calculating :
This value satisfies the given condition .
Final Answer: The value of is 9.