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Determine Atomic Number from Successive Ionization Enthalpies

The 1st1^{\text{st}}, 2nd2^{\text{nd}}, and 3rd3^{\text{rd}} ionization enthalpies, I1,I2,I_1, I_2, and I3I_3, of four elements having atomic numbers n,n+1,n+2,n, n+1, n+2, and n+3n+3, where n<10n < 10, are provided in the table. Find the value of nn.

Atomic numberIonization Enthalpy (kJ/mol)\cline2−4I1I2I3n168133746050n+1208139526122n+249645626910n+373814517733\begin{array}{|c|c|c|c|}\hline \text{Atomic number} & \text{Ionization Enthalpy (kJ/mol)} \\ \cline{2-4} & I_1 & I_2 & I_3 \\ \hline n & 1681 & 3374 & 6050 \\ \hline n+1 & 2081 & 3952 & 6122 \\ \hline n+2 & 496 & 4562 & 6910 \\ \hline n+3 & 738 & 1451 & 7733 \\ \hline \end{array}
Official Numerical Answer9

Step-by-Step Solution

To determine the atomic number nn, we analyze the trends and sudden jumps in the given ionization enthalpies (I1,I2,I3I_1, I_2, I_3):

  1. Analyzing Element (n+2)(n + 2):

    • I1=496 kJ/molI_1 = 496 \text{ kJ/mol}
    • I2=4562 kJ/molI_2 = 4562 \text{ kJ/mol}

    The large ratio I2I1≈9.2\frac{I_2}{I_1} \approx 9.2 indicates a massive jump between the first and second ionization energies. This signifies that the removal of the second electron involves removing an electron from a stable, fully filled noble gas shell. Therefore, the element with atomic number (n+2)(n + 2) has 11 valence electron and belongs to Group 1 (Alkali metals).

  2. Analyzing Element (n+3)(n + 3):

    • I1=738 kJ/molI_1 = 738 \text{ kJ/mol}
    • I2=1451 kJ/molI_2 = 1451 \text{ kJ/mol}
    • I3=7733 kJ/molI_3 = 7733 \text{ kJ/mol}

    Here, the significant jump occurs between I2I_2 and I3I_3 (I3I2≈5.3\frac{I_3}{I_2} \approx 5.3), which indicates that this element has 22 valence electrons and belongs to Group 2 (Alkaline earth metals).

  3. Identifying the specific elements:

    • The first ionization enthalpy of 496 kJ/mol496 \text{ kJ/mol} corresponds specifically to Sodium (Na\text{Na}), which has an atomic number Z=11Z = 11.
    • Consequently, the element (n+3)(n+3) with Z=12Z = 12 is Magnesium (Mg\text{Mg}).
    • The elements nn and n+1n+1 correspond to Fluorine (F\text{F}, Z=9Z = 9) and Neon (Ne\text{Ne}, Z=10Z = 10) respectively, which matches the high I1I_1 values of 1681 kJ/mol1681 \text{ kJ/mol} and 2081 kJ/mol2081 \text{ kJ/mol}.
  4. Calculating nn: n+2=11  ⟹  n=9n + 2 = 11 \implies n = 9

This value satisfies the given condition n<10n < 10.

Final Answer: The value of nn is 9.