JEE Challenger
More from General Principles and Processes of Isolation of Elements

Chemical Formulas of Calamine Malachite Magnetite and Cryolite

Identify the chemical formulas corresponding to calamine, malachite, magnetite, and cryolite, respectively:

Options

A

ZnSO4,CuCO3,Fe2O3,AlF3\text{ZnSO}_4, \text{CuCO}_3, \text{Fe}_2\text{O}_3, \text{AlF}_3

B

ZnSO4,Cu(OH)2,Fe3O4,Na3AlF6\text{ZnSO}_4, \text{Cu}(\text{OH})_2, \text{Fe}_3\text{O}_4, \text{Na}_3\text{AlF}_6

C

ZnCO3,CuCO3⋅Cu(OH)2,Fe3O4,Na3AlF6\text{ZnCO}_3, \text{CuCO}_3 \cdot \text{Cu}(\text{OH})_2, \text{Fe}_3\text{O}_4, \text{Na}_3\text{AlF}_6

Correct
D

ZnCO3,CuCO3,Fe2O3,Na3AlF6\text{ZnCO}_3, \text{CuCO}_3, \text{Fe}_2\text{O}_3, \text{Na}_3\text{AlF}_6

Step-by-Step Solution

To determine the correct chemical formulas corresponding to each mineral, we recall their chemical compositions:

  1. Calamine: It is an ore of zinc primarily composed of zinc carbonate. Chemical Formula: ZnCO3\text{Chemical Formula: } \text{ZnCO}_3

  2. Malachite: It is a basic copper carbonate mineral. Chemical Formula: CuCO3⋅Cu(OH)2\text{Chemical Formula: } \text{CuCO}_3 \cdot \text{Cu}(\text{OH})_2

  3. Magnetite: It is a magnetic iron oxide mineral containing both iron(II) and iron(III) oxidation states (mixed oxide of iron). Chemical Formula: Fe3O4\text{Chemical Formula: } \text{Fe}_3\text{O}_4

  4. Cryolite: It is a compound mineral of sodium, aluminium, and fluorine, used in the metallurgy of aluminium. Chemical Formula: Na3AlF6\text{Chemical Formula: } \text{Na}_3\text{AlF}_6

Matching these formulas respectively gives: Calamine⟶ZnCO3\text{Calamine} \longrightarrow \text{ZnCO}_3 Malachite⟶CuCO3⋅Cu(OH)2\text{Malachite} \longrightarrow \text{CuCO}_3 \cdot \text{Cu}(\text{OH})_2 Magnetite⟶Fe3O4\text{Magnetite} \longrightarrow \text{Fe}_3\text{O}_4 Cryolite⟶Na3AlF6\text{Cryolite} \longrightarrow \text{Na}_3\text{AlF}_6

This sequence matches option (C).

Correct Option: (C)