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Calculate Exponent Y for Molar Solubility of Lead Sulfate

In a given solution, the concentrations of H2SO4\text{H}_2\text{SO}_4 and Na2SO4\text{Na}_2\text{SO}_4 are 1 M1\text{ M} and 1.8×10−2 M1.8 \times 10^{-2}\text{ M}, respectively. The molar solubility of PbSO4\text{PbSO}_4 in this solution is expressed as X×10−Y M\text{X} \times 10^{-\text{Y}}\text{ M} in scientific notation. Determine the value of Y\text{Y}.

[Given: The solubility product of PbSO4\text{PbSO}_4 is Ksp=1.6×10−8K_{sp} = 1.6 \times 10^{-8}. For H2SO4\text{H}_2\text{SO}_4, Ka1K_{a1} is very large and Ka2=1.2×10−2K_{a2} = 1.2 \times 10^{-2}]

Official Numerical Answer6

Step-by-Step Solution

To find the value of YY, we first determine the equilibrium concentration of SO42−\text{SO}_4^{2-} in the given solution. Since Ka1K_{a1} of H2SO4\text{H}_2\text{SO}_4 is very large, H2SO4\text{H}_2\text{SO}_4 dissociates completely into 1 M1\text{ M} H+\text{H}^+ and 1 M1\text{ M} HSO4−\text{HSO}_4^-. Using the second dissociation constant Ka2=[H+][SO42−][HSO4−]=1.2×10−2K_{a2} = \frac{[\text{H}^+][\text{SO}_4^{2-}]}{[\text{HSO}_4^-]} = 1.2 \times 10^{-2}, with [H+]≈1 M[\text{H}^+] \approx 1\text{ M} and [HSO4−]≈1 M[\text{HSO}_4^-] \approx 1\text{ M}, the concentration of sulphate ion is given by [SO42−]=Ka2=1.2×10−2 M[\text{SO}_4^{2-}] = K_{a2} = 1.2 \times 10^{-2}\text{ M}. The molar solubility SS of PbSO4\text{PbSO}_4 is then calculated from the solubility product Ksp=[Pb2+][SO42−]=1.6×10−8K_{sp} = [\text{Pb}^{2+}][\text{SO}_4^{2-}] = 1.6 \times 10^{-8}, yielding S=1.6×10−81.2×10−2=1.33×10−6 MS = \frac{1.6 \times 10^{-8}}{1.2 \times 10^{-2}} = 1.33 \times 10^{-6}\text{ M}. Expressing this in scientific notation as X×10−Y MX \times 10^{-Y}\text{ M}, we find Y=6Y = 6.

Calculate Exponent Y for Molar Solubility of Lead Sulfate | Chemistry PYQ Solution - JEE Challenger