To find the value of x, we determine the number of silver (Ag) atoms present on the given surface area.
Step 1: Calculate the molar volume of silver (Vm)
Given:
- Molar mass of Ag, M=108 g mol−1
- Density of Ag, ρ=10.5 g cm−3
The molar volume is given by:
Vm=ρM=10.5 g cm−3108 g mol−1≈10.286 cm3mol−1=10.286×10−6 m3mol−1
Step 2: Calculate the volume occupied by a single silver atom (Vatom)
Using Avogadro's number (NA≈6.022×1023 mol−1):
Vatom=NAVm=6.022×1023 mol−110.286×10−6 m3mol−1≈1.708×10−29 m3
Step 3: Estimate the effective linear dimension (d) of a silver atom
Assuming each atom occupies a cubic volume element of side length d:
d=(Vatom)1/3=(1.708×10−29 m3)1/3≈2.575×10−10 m
Step 4: Calculate the surface area occupied by a single atom (Aatom)
The cross-sectional area occupied by an atom on the surface is:
Aatom=d2=(2.575×10−10 m)2≈6.63×10−20 m2
Step 5: Calculate the total number of atoms on the surface
Given total surface area A=10−12 m2:
N=AatomA=6.63×10−20 m210−12 m2≈1.51×107
Comparing N=1.51×107 with the standard scientific notation y×10x (where 1≤y<10):
x=7