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Calculate Exponent in Scientific Notation for Silver Surface Atoms

Silver (atomic weight =108 g mol−1= 108\text{ g mol}^{-1}) has a density of 10.5 g cm−310.5\text{ g cm}^{-3}. The number of silver atoms on a surface of area 10−12 m210^{-12}\text{ m}^2 can be expressed in scientific notation as y×10xy \times 10^x. The value of xx is

Official Numerical Answer7

Topics & Concepts

Step-by-Step Solution

To find the value of xx, we determine the number of silver (Ag\text{Ag}) atoms present on the given surface area.

Step 1: Calculate the molar volume of silver (VmV_m)
Given:

  • Molar mass of Ag\text{Ag}, M=108 g mol−1M = 108 \text{ g mol}^{-1}
  • Density of Ag\text{Ag}, ρ=10.5 g cm−3\rho = 10.5 \text{ g cm}^{-3}

The molar volume is given by:
Vm=Mρ=108 g mol−110.5 g cm−3≈10.286 cm3mol−1=10.286×10−6 m3mol−1V_m = \frac{M}{\rho} = \frac{108 \text{ g mol}^{-1}}{10.5 \text{ g cm}^{-3}} \approx 10.286 \text{ cm}^3 \text{mol}^{-1} = 10.286 \times 10^{-6} \text{ m}^3 \text{mol}^{-1}

Step 2: Calculate the volume occupied by a single silver atom (VatomV_{\text{atom}})
Using Avogadro's number (NA≈6.022×1023 mol−1N_A \approx 6.022 \times 10^{23} \text{ mol}^{-1}):
Vatom=VmNA=10.286×10−6 m3mol−16.022×1023 mol−1≈1.708×10−29 m3V_{\text{atom}} = \frac{V_m}{N_A} = \frac{10.286 \times 10^{-6} \text{ m}^3 \text{mol}^{-1}}{6.022 \times 10^{23} \text{ mol}^{-1}} \approx 1.708 \times 10^{-29} \text{ m}^3

Step 3: Estimate the effective linear dimension (dd) of a silver atom
Assuming each atom occupies a cubic volume element of side length dd:
d=(Vatom)1/3=(1.708×10−29 m3)1/3≈2.575×10−10 md = \left(V_{\text{atom}}\right)^{1/3} = \left(1.708 \times 10^{-29} \text{ m}^3\right)^{1/3} \approx 2.575 \times 10^{-10} \text{ m}

Step 4: Calculate the surface area occupied by a single atom (AatomA_{\text{atom}})
The cross-sectional area occupied by an atom on the surface is:
Aatom=d2=(2.575×10−10 m)2≈6.63×10−20 m2A_{\text{atom}} = d^2 = \left(2.575 \times 10^{-10} \text{ m}\right)^2 \approx 6.63 \times 10^{-20} \text{ m}^2

Step 5: Calculate the total number of atoms on the surface
Given total surface area A=10−12 m2A = 10^{-12} \text{ m}^2:
N=AAatom=10−12 m26.63×10−20 m2≈1.51×107N = \frac{A}{A_{\text{atom}}} = \frac{10^{-12} \text{ m}^2}{6.63 \times 10^{-20} \text{ m}^2} \approx 1.51 \times 10^7

Comparing N=1.51×107N = 1.51 \times 10^7 with the standard scientific notation y×10xy \times 10^x (where 1≤y<101 \le y < 10):
x=7x = 7