JEE Challenger
More from Dual Nature of Radiation and Matter

Work Function of Metal from Photoelectron Speed Ratios

A metallic surface is illuminated by light of two distinct wavelengths, 248 nm248\text{ nm} and 310 nm310\text{ nm}. The maximum speeds achieved by the emitted photoelectrons for these wavelengths are u1u_1 and u2u_2, respectively. If the ratio u1:u2=2:1u_1 : u_2 = 2 : 1 and hc=1240 eV nmhc = 1240\text{ eV nm}, then the work function of the metal is approximately

Options

A

3.7 eV3.7\text{ eV}

Correct
B

3.2 eV3.2\text{ eV}

C

2.8 eV2.8\text{ eV}

D

2.5 eV2.5\text{ eV}

Step-by-Step Solution

According to Einstein's photoelectric equation, the maximum kinetic energy of the emitted photoelectrons is given by: Kmax⁡=12mu2=E−ΦK_{\max} = \frac{1}{2} m u^2 = E - \Phi

where:

  • E=hcλE = \frac{hc}{\lambda} is the energy of the incident photon,
  • Φ\Phi is the work function of the metal,
  • mm is the mass of an electron, and
  • uu is the maximum speed of the emitted photoelectrons.

Given hc=1240 eV nmhc = 1240\text{ eV nm}, we can calculate the energy of the incident photons for both wavelengths: For λ1=248 nm\lambda_1 = 248\text{ nm}: E1=1240 eV nm248 nm=5 eVE_1 = \frac{1240\text{ eV nm}}{248\text{ nm}} = 5\text{ eV}

For λ2=310 nm\lambda_2 = 310\text{ nm}: E2=1240 eV nm310 nm=4 eVE_2 = \frac{1240\text{ eV nm}}{310\text{ nm}} = 4\text{ eV}

The corresponding maximum kinetic energies are: Kmax⁡,1=12mu12=5−ΦK_{\max, 1} = \frac{1}{2} m u_1^2 = 5 - \Phi Kmax⁡,2=12mu22=4−ΦK_{\max, 2} = \frac{1}{2} m u_2^2 = 4 - \Phi

Given that the ratio of the maximum speeds is: u1u2=21\frac{u_1}{u_2} = \frac{2}{1}

The ratio of their maximum kinetic energies is: Kmax⁡,1Kmax⁡,2=(u1u2)2=(21)2=4\frac{K_{\max, 1}}{K_{\max, 2}} = \left(\frac{u_1}{u_2}\right)^2 = \left(\frac{2}{1}\right)^2 = 4

Substituting the expressions for kinetic energy: 5−Φ4−Φ=4\frac{5 - \Phi}{4 - \Phi} = 4

Solving for Φ\Phi: 5−Φ=4(4−Φ)5 - \Phi = 4(4 - \Phi) 5−Φ=16−4Φ5 - \Phi = 16 - 4\Phi 3Φ=113\Phi = 11 Φ=113 eV≈3.67 eV≈3.7 eV\Phi = \frac{11}{3}\text{ eV} \approx 3.67\text{ eV} \approx 3.7\text{ eV}

Therefore, the work function of the metal is approximately 3.7 eV3.7\text{ eV}.

Correct Option: (A)