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Wavelength of Emitted Photon in Hydrogen Atom Transition

In the hydrogen atom, the electron makes a transition from the higher orbit (ii) to a lower orbit (ff). The ratio of the radius of the orbits in given by ri:rf=16:4r_i : r_f = 16 : 4. The wavelength of photon emitted due to this transition is _______ nm. (Given Rydberg constant =1.0973×107 m1= 1.0973 \times 10^7\text{ m}^{-1})

Options

A

121

B

242

C

486

Correct
D

974

Topics & Concepts

AtomsBohr Model

Step-by-Step Solution

To find the wavelength of the emitted photon during the electronic transition in the hydrogen atom, we start from the expression for the radius of the nthn^{\text{th}} orbit in Bohr's model:

rnn2r_n \propto n^2

Thus, the radii of the initial orbit rir_i and final orbit rfr_f are related to their respective principal quantum numbers nin_i and nfn_f by:

rirf=(ninf)2\frac{r_i}{r_f} = \left(\frac{n_i}{n_f}\right)^2

Given that the ratio of the radii is ri:rf=16:4r_i : r_f = 16 : 4, we can write:

ni2nf2=164\frac{n_i^2}{n_f^2} = \frac{16}{4}

Since nin_i and nfn_f are positive integers, this directly implies: ni=4andnf=2n_i = 4 \quad \text{and} \quad n_f = 2

Now, using the Rydberg formula for hydrogen, the wavelength λ\lambda of the emitted photon during the transition from ni=4n_i = 4 to nf=2n_f = 2 is given by:

1λ=R(1nf21ni2)\frac{1}{\lambda} = R \left( \frac{1}{n_f^2} - \frac{1}{n_i^2} \right)

where R=1.0973×107 m1R = 1.0973 \times 10^7 \text{ m}^{-1} is the Rydberg constant.

Substituting the values of nin_i and nfn_f:

1λ=R(122142)\frac{1}{\lambda} = R \left( \frac{1}{2^2} - \frac{1}{4^2} \right)

1λ=R(14116)=316R\frac{1}{\lambda} = R \left( \frac{1}{4} - \frac{1}{16} \right) = \frac{3}{16} R

Solving for λ\lambda:

λ=163R\lambda = \frac{16}{3 R}

Substitute R=1.0973×107 m1R = 1.0973 \times 10^7 \text{ m}^{-1}:

λ=163×1.0973×107 m1=163.2919×107 m\lambda = \frac{16}{3 \times 1.0973 \times 10^7 \text{ m}^{-1}} = \frac{16}{3.2919 \times 10^7} \text{ m}

λ4.8604×107 m=486 nm\lambda \approx 4.8604 \times 10^{-7} \text{ m} = 486 \text{ nm}

Hence, the wavelength of the emitted photon is 486 nm, which corresponds to Option C.

Wavelength of Emitted Photon in Hydrogen Atom Transition | Physics PYQ Solution - JEE Challenger