JEE Challenger
More from p-Block Elements (Group 15-18)

Total Number of Gases Released in Xenon Hexafluoride Hydrolysis Scheme

Under ambient laboratory conditions, count the total number of gaseous species evolved as products in the final reaction step of the reaction scheme depicted below:

Question Diagram 1

Options

A

0

B

1

C

2

Correct
D

3

Step-by-Step Solution

To determine the total number of gaseous species evolved as products in the final step of the given reaction scheme, we analyze the sequence step-by-step:

Step 1: Complete Hydrolysis of XeF6\text{XeF}_6

When xenon hexafluoride (XeF6\text{XeF}_6) undergoes complete hydrolysis, it yields xenon trioxide (XeO3\text{XeO}_3) and hydrogen fluoride (HF\text{HF}): XeF6+3H2O→XeO3+6HF\text{XeF}_6 + 3\text{H}_2\text{O} \rightarrow \text{XeO}_3 + 6\text{HF}

Thus, compound P\mathbf{P} is xenon trioxide (XeO3\text{XeO}_3).


Step 2: Reaction of XeO3\text{XeO}_3 with Hydroxide Ions (OH−\text{OH}^-)

In an alkaline solution, XeO3\text{XeO}_3 reacts with OH−\text{OH}^- to form the hydrogen xenate ion (HXeO4−\text{HXeO}_4^-): XeO3+OH−→HXeO4−\text{XeO}_3 + \text{OH}^- \rightarrow \text{HXeO}_4^-

Thus, species Q\mathbf{Q} is the hydrogen xenate ion (HXeO4−\text{HXeO}_4^-).


Step 3: Slow Disproportionation of HXeO4−\text{HXeO}_4^-

In an alkaline medium, the hydrogen xenate ion (Q\mathbf{Q}) slowly undergoes disproportionation to form perxenate ion (XeO64−\text{XeO}_6^{4-}), xenon gas (Xe\text{Xe}), oxygen gas (O2\text{O}_2), and water (H2O\text{H}_2\text{O}): 2HXeO4−(aq)+2OH−(aq)→XeO64−(aq)+Xe(g)+O2(g)+2H2O(l)2\text{HXeO}_4^-(aq) + 2\text{OH}^-(aq) \rightarrow \text{XeO}_6^{4-}(aq) + \text{Xe}(g) + \text{O}_2(g) + 2\text{H}_2\text{O}(l)


Conclusion

In the final reaction step, the gaseous species evolved are:

  1. Xenon gas (Xe\text{Xe})
  2. Oxygen gas (O2\text{O}_2)

Thus, the total number of gaseous species released in the final step is 22.

Correct Option: (C)