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More from p-Block Elements (Group 15-18)

Total Lone Pairs in Xenon Compound Y

When XeF4\text{XeF}_4 reacts with O2F2\text{O}_2\text{F}_2 at 143 K143\text{ K}, a xenon compound Y\text{Y} is produced. Calculate the total number of lone pairs of electrons present across the entire molecule of Y\text{Y}.

Official Numerical Answer19

Step-by-Step Solution

To determine the total number of lone pairs of electrons in the xenon compound Y\text{Y}, we first identify the chemical reaction taking place.

Step 1: Chemical Reaction

When xenon tetrafluoride (XeF4\text{XeF}_4) reacts with dioxygen difluoride (O2F2\text{O}_2\text{F}_2) at 143 K143\text{ K}, O2F2\text{O}_2\text{F}_2 acts as a fluorinating agent: XeF4+O2F2→143 KXeF6+O2\text{XeF}_4 + \text{O}_2\text{F}_2 \xrightarrow{143\text{ K}} \text{XeF}_6 + \text{O}_2

Thus, the xenon compound Y\text{Y} is xenon hexafluoride (XeF6\text{XeF}_6).


Step 2: Calculate Lone Pairs on the Central Xenon Atom (Xe\text{Xe})

  • Valence electrons of Xenon (Xe\text{Xe}) = 88
  • Number of fluorine atoms bonded to Xe\text{Xe} = 66
  • Electrons used in forming 66 single Xe−F\text{Xe}-\text{F} bonds = 66
  • Remaining valence electrons on Xe=8−6=2 electrons\text{Xe} = 8 - 6 = 2\text{ electrons}
  • Number of lone pairs on Xe=22=1 lone pair\text{Xe} = \frac{2}{2} = 1\text{ lone pair}

Step 3: Calculate Lone Pairs on the Fluorine Atoms (F\text{F})

  • Valence electrons of each Fluorine atom (F\text{F}) = 77
  • Electrons used in forming 11 single bond = 11
  • Non-bonding electrons on each F\text{F} atom = 7−1=6 electrons7 - 1 = 6\text{ electrons} (3 lone pairs3\text{ lone pairs})
  • Number of lone pairs on 66 fluorine atoms = 6×3=18 lone pairs6 \times 3 = 18\text{ lone pairs}

Step 4: Total Lone Pairs Across the Entire Molecule

Total Lone Pairs=(Lone pairs on Xe)+(Lone pairs on 6 F atoms)\text{Total Lone Pairs} = (\text{Lone pairs on Xe}) + (\text{Lone pairs on } 6\text{ F atoms}) Total Lone Pairs=1+18=19\text{Total Lone Pairs} = 1 + 18 = 19

The total number of lone pairs of electrons present across the whole molecule of Y\text{Y} is 19.