Statements on Covalency and Oxidation State of Oxygen
Given below are two statements:
Statement I: The covalency of oxygen is generally two but it can exceed upto four. The oxidation state of oxygen in is and in it is .
Statement II: The anomalous behaviour of oxygen when compared to the other elements of group 16 is due to its small size and high electronegativity.
In the light of the above statements, choose the correct answer from the options given below
Options
Both Statement I and Statement II are true
Both Statement I and Statement II are false
Statement I is true but Statement II is false
Statement I is false but Statement II is true
Topics & Concepts
Step-by-Step Solution
To evaluate the given statements, let us analyze them individually based on the chemical properties of oxygen and periodic trends:
Analysis of Statement I:
-
Covalency of Oxygen:
- Oxygen belongs to the second period of the periodic table and has the valence shell electronic configuration of .
- Because it lacks vacant -orbitals, its maximum coordination number or valence shell capacity is restricted to 8 electrons (utilizing one orbital and three orbitals). Hence, its maximum covalency is , though in practice, it usually exhibits a covalency of (or , as in ). Thus, its covalency generally is and can go up to a maximum of .
-
Oxidation State of Oxygen:
- In : Oxygen is more electronegative than sulfur (). Sulfur is in the oxidation state, giving oxygen its typical oxidation state of .
- In : Fluorine is the most electronegative element () and carries an oxidation state of . Consequently, for the neutral molecule :
Therefore, Statement I is true.
Analysis of Statement II:
- Oxygen exhibits anomalous behaviour compared to other elements of Group 16 (, , , ).
- This anomalous nature is primarily attributed to:
- Small atomic/ionic size.
- High electronegativity.
- High ionization enthalpy.
- Non-availability of vacant -orbitals in its valence shell.
Therefore, Statement II is true.
Conclusion:
Since both Statement I and Statement II are true, the correct option is A.