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Statements on Covalency and Oxidation State of Oxygen

Given below are two statements:

Statement I: The covalency of oxygen is generally two but it can exceed upto four. The oxidation state of oxygen in SO2\text{SO}_2 is 2-2 and in OF2\text{OF}_2 it is +2+2.

Statement II: The anomalous behaviour of oxygen when compared to the other elements of group 16 is due to its small size and high electronegativity.

In the light of the above statements, choose the correct answer from the options given below

Options

A

Both Statement I and Statement II are true

Correct
B

Both Statement I and Statement II are false

C

Statement I is true but Statement II is false

D

Statement I is false but Statement II is true

Step-by-Step Solution

To evaluate the given statements, let us analyze them individually based on the chemical properties of oxygen and periodic trends:

Analysis of Statement I:

  1. Covalency of Oxygen:

    • Oxygen belongs to the second period of the periodic table and has the valence shell electronic configuration of 2s22p42s^2 2p^4.
    • Because it lacks vacant dd-orbitals, its maximum coordination number or valence shell capacity is restricted to 8 electrons (utilizing one 2s2s orbital and three 2p2p orbitals). Hence, its maximum covalency is 44, though in practice, it usually exhibits a covalency of 22 (or 33, as in H3O+\text{H}_3\text{O}^+). Thus, its covalency generally is 22 and can go up to a maximum of 44.
  2. Oxidation State of Oxygen:

    • In SO2\text{SO}_2: Oxygen is more electronegative than sulfur (χO>χS\chi_{\text{O}} > \chi_{\text{S}}). Sulfur is in the +4+4 oxidation state, giving oxygen its typical oxidation state of 2-2.
    • In OF2\text{OF}_2: Fluorine is the most electronegative element (χF>χO\chi_{\text{F}} > \chi_{\text{O}}) and carries an oxidation state of 1-1. Consequently, for the neutral molecule OF2\text{OF}_2: O.S. of O+2(1)=0    O.S. of O=+2\text{O.S. of O} + 2(-1) = 0 \implies \text{O.S. of O} = +2

Therefore, Statement I is true.


Analysis of Statement II:

  • Oxygen exhibits anomalous behaviour compared to other elements of Group 16 (S\text{S}, Se\text{Se}, Te\text{Te}, Po\text{Po}).
  • This anomalous nature is primarily attributed to:
    1. Small atomic/ionic size.
    2. High electronegativity.
    3. High ionization enthalpy.
    4. Non-availability of vacant dd-orbitals in its valence shell.

Therefore, Statement II is true.


Conclusion:

Since both Statement I and Statement II are true, the correct option is A.

Statements on Covalency and Oxidation State of Oxygen | Chemistry PYQ Solution - JEE Challenger