JEE Challenger
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Separation of Organic Compounds and Natural Extracts

Given below are two statements:

Statement I : A mixture of C12H22O11\text{C}_{12}\text{H}_{22}\text{O}_{11} (sugar) and NaCl\text{NaCl} can be separated by dissolving sugar in alcohol, due to differential solubility.

Statement II : Rose essence from rose petals is seperated by steam distillation due to its high volatility and insolubility in H2O\text{H}_2\text{O}.

In the light of the above statements, choose the correct answer from the options given below:

Options

A

Both Statement I and Statement II are true

Correct
B

Both Statement I and Statement II are false

C

Statement I is true but Statement II is false

D

Statement I is false but Statement II is true

Step-by-Step Solution

To determine the correctness of the given statements, let us analyze them individually:

  1. Analysis of Statement I:

    • Sugar (C12H22O11\text{C}_{12}\text{H}_{22}\text{O}_{11}) is a polar covalent organic compound that dissolves in alcohol (ethanol) due to favorable hydrogen bonding interactions.
    • Sodium chloride (NaCl\text{NaCl}) is an ionic solid with high lattice energy that is virtually insoluble in alcohol.
    • Because of this differential solubility, adding ethanol to a mixture of sugar and salt dissolves the sugar completely while leaving NaCl\text{NaCl} as an undissolved residue, which can be easily filtered off.
    • Thus, Statement I is true.
  2. Analysis of Statement II:

    • Steam distillation is a separation technique used for purifying liquids that are steam-volatile (have high vapor pressure at temperatures near the boiling point of water) and immiscible/insoluble in water.
    • Rose essence (essential oil from rose petals) contains organic compounds that are volatile in steam and insoluble in water, allowing them to be carried over with steam and condensed separately.
    • Thus, Statement II is true.

Therefore, both Statement I and Statement II are true.

Correct Answer: A (Both Statement I and Statement II are true)

Separation of Organic Compounds and Natural Extracts | Chemistry PYQ Solution - JEE Challenger