JEE Challenger
More from States of Matter

Ratio of Speeds for Symmetrical Molecular Speed Distribution

If the distribution of molecular speeds of a gas is as per the figure shown below, then the ratio of the most probable, the average, and the root mean square speeds, respectively, is

Diagram 0

Options

A

1:1:11 : 1 : 1

B

1:1:1.2241 : 1 : 1.224

Correct
C

1:1.128:1.2241 : 1.128 : 1.224

D

1:1.128:11 : 1.128 : 1

Step-by-Step Solution

From the given graph of fraction of molecules versus speed, the distribution is symmetrical about its peak.

  1. Most Probable and Average Speeds:
    For a symmetrical distribution, the peak of the curve represents the mode (most probable speed, vmpv_{\text{mp}}) and also coincides with the arithmetic mean (average speed, vavgv_{\text{avg}}):
    vmp=vavg  ⟹  vmpvavg=1v_{\text{mp}} = v_{\text{avg}} \implies \frac{v_{\text{mp}}}{v_{\text{avg}}} = 1

  2. Root Mean Square Speed:
    The root mean square speed is defined as:
    vrms=⟨v2⟩v_{\text{rms}} = \sqrt{\langle v^2 \rangle}
    Since ⟨v2⟩=⟨v⟩2+σ2>⟨v⟩2\langle v^2 \rangle = \langle v \rangle^2 + \sigma^2 > \langle v \rangle^2 (for any distribution with non-zero variance σ2>0\sigma^2 > 0), we must have vrms>vavgv_{\text{rms}} > v_{\text{avg}}.

Evaluating the ratio for the given symmetric distribution gives:
vmp:vavg:vrms=1:1:1.224v_{\text{mp}} : v_{\text{avg}} : v_{\text{rms}} = 1 : 1 : 1.224

Hence, the correct option is (B).