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Ratio of Momentum of Photons in Balmer Series

The ratio of momentum of the photons of the 1st1^{\text{st}} and 2nd2^{\text{nd}} line of Balmer series of Hydrogen atoms is α/β\alpha/\beta. The possible values of α\alpha and β\beta are:

Options

A

27 and 20

B

3 and 16

C

5 and 36

D

20 and 27

Correct

Topics & Concepts

AtomsBohr Model

Step-by-Step Solution

The momentum pp of a photon is directly proportional to its energy EE (or wavenumber 1λ\frac{1}{\lambda}): p=Ec=hλp = \frac{E}{c} = \frac{h}{\lambda}

For a hydrogen atom, the wavenumber for a transition from an upper energy level n2n_2 to a lower energy level n1n_1 is given by the Rydberg formula: 1λ=R(1n121n22)\frac{1}{\lambda} = R \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) where RR is the Rydberg constant.

For the Balmer series, the lower energy level is n1=2n_1 = 2.

  1. For the 1st1^{\text{st}} line of the Balmer series (n2=3n1=2n_2 = 3 \to n_1 = 2): 1λ1=R(122132)=R(1419)=536R\frac{1}{\lambda_1} = R \left( \frac{1}{2^2} - \frac{1}{3^2} \right) = R \left( \frac{1}{4} - \frac{1}{9} \right) = \frac{5}{36}R Therefore, the momentum of the photon emitted in the 1st1^{\text{st}} line is: p1=hR(536)p_1 = h R \left( \frac{5}{36} \right)

  2. For the 2nd2^{\text{nd}} line of the Balmer series (n2=4n1=2n_2 = 4 \to n_1 = 2): 1λ2=R(122142)=R(14116)=316R\frac{1}{\lambda_2} = R \left( \frac{1}{2^2} - \frac{1}{4^2} \right) = R \left( \frac{1}{4} - \frac{1}{16} \right) = \frac{3}{16}R Therefore, the momentum of the photon emitted in the 2nd2^{\text{nd}} line is: p2=hR(316)p_2 = h R \left( \frac{3}{16} \right)

  3. Ratio of the momenta: p1p2=1λ11λ2=536316=536×163=2027\frac{p_1}{p_2} = \frac{\frac{1}{\lambda_1}}{\frac{1}{\lambda_2}} = \frac{\frac{5}{36}}{\frac{3}{16}} = \frac{5}{36} \times \frac{16}{3} = \frac{20}{27}

Given that the ratio of the momentum is αβ\frac{\alpha}{\beta}: αβ=2027\frac{\alpha}{\beta} = \frac{20}{27}

Thus, the possible values of α\alpha and β\beta are 2020 and 2727 respectively.

Correct Option: D (20 and 27)

Ratio of Momentum of Photons in Balmer Series | Physics PYQ Solution - JEE Challenger