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Physical and Chemical Characteristics of Interstitial Compounds

Which of the following is NOT a physical or chemical characteristics of interstitial compounds?

Options

A

They have high melting points, higher than those of pure metals.

B

They are very soft and ionic in nature.

Correct
C

They retain metallic conductivity.

D

They are chemically inert and usually non-stoichiometric.

Topics & Concepts

Step-by-Step Solution

Interstitial compounds are formed when small non-metal atoms like H\text{H}, C\text{C}, or N\text{N} are trapped inside the interstitial sites (voids) of the crystal lattices of transition metals.

The characteristic physical and chemical properties of interstitial compounds as defined by NCERT chemistry principles are:

  1. Melting Point: They possess very high melting points, which are significantly higher than those of pure metals due to enhanced lattice strength.
  2. Hardness: They are extremely hard; some borides even approach diamond in hardness. Thus, describing them as "very soft" is incorrect.
  3. Conductivity: They retain metallic conductivity similar to their parent transition metals.
  4. Chemical Nature: They are chemically inert and generally non-stoichiometric in nature (e.g., TiH1.7\text{TiH}_{1.7}, VH0.56\text{VH}_{0.56}, Fe3C\text{Fe}_3\text{C}). They are neither typical ionic nor covalent compounds.

Evaluating the given options:

  • Option A: Correct characteristic.
  • Option B: Incorrect characteristic, because interstitial compounds are extremely hard (not soft) and are neither ionic nor covalent.
  • Option C: Correct characteristic.
  • Option D: Correct characteristic.

Since the question asks for the option that is NOT a physical or chemical characteristic of interstitial compounds, Option B is the incorrect statement.

Hence, the correct option is B.

Physical and Chemical Characteristics of Interstitial Compounds | Chemistry PYQ Solution - JEE Challenger