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Partial Pressure of Carbon Monoxide at Equilibrium

Solid carbon, CaO\text{CaO} and CaCO3\text{CaCO}_3 are mixed and allowed to attain equilibrium at T KT\text{ K}.

CaCO3(s)CaO(s)+CO2(g)Kp1=0.08 atmC(s)+CO2(g)2CO(g)Kp2=2 atm\begin{array}{ll} \text{CaCO}_3(\text{s}) \rightleftharpoons \text{CaO}(\text{s}) + \text{CO}_2(\text{g}) & K_{p1} = 0.08\text{ atm} \\ \text{C}(\text{s}) + \text{CO}_2(\text{g}) \rightleftharpoons 2\text{CO}(\text{g}) & K_{p2} = 2\text{ atm} \end{array}

The partial pressure of CO\text{CO} is _____ ×101 atm\times 10^{-1}\text{ atm}.

Official Numerical Answer4

Topics & Concepts

Step-by-Step Solution

To find the partial pressure of CO\text{CO} at equilibrium, we first determine the partial pressure of CO2\text{CO}_2 from the equilibrium constant of the first reaction, Kp1=PCO2=0.08 atmK_{p1} = P_{\text{CO}_2} = 0.08\text{ atm}. Using the equilibrium expression for the second reaction, Kp2=PCO2PCO2K_{p2} = \frac{P_{\text{CO}}^2}{P_{\text{CO}_2}}, we substitute Kp2=2 atmK_{p2} = 2\text{ atm} and PCO2=0.08 atmP_{\text{CO}_2} = 0.08\text{ atm} to get PCO2=2×0.08=0.16 atm2P_{\text{CO}}^2 = 2 \times 0.08 = 0.16\text{ atm}^2. Taking the square root gives PCO=0.4 atm=4×101 atmP_{\text{CO}} = 0.4\text{ atm} = 4 \times 10^{-1}\text{ atm}. Thus, the required value is 44.

Partial Pressure of Carbon Monoxide at Equilibrium | Chemistry PYQ Solution - JEE Challenger