JEE Challenger
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Orbital Angular Momentum Quantum Number of State S2

Comprehension Passage

The hydrogen-like species Li2+\text{Li}^{2+} is in a spherically symmetric state S1\text{S}_1 with one radial node. Upon absorbing light the ion undergoes transition to a state S2\text{S}_2. The state S2\text{S}_2 has one radial node and its energy is equal to the ground state energy of the hydrogen atom.

The orbital angular momentum quantum number of the state S2\text{S}_2 is

Options

A

0

B

1

Correct
C

2

D

3

Step-by-Step Solution

To find the orbital angular momentum quantum number (ll) of the state S2\text{S}_2, we analyze the information given in the passage:

  1. Energy of State S2\text{S}_2:
    The energy of a hydrogen-like species with atomic number ZZ in a state with principal quantum number nn is given by:
    En=−EHZ2n2E_n = -E_H \frac{Z^2}{n^2}
    where EH=13.6 eVE_H = 13.6 \text{ eV} is the ground state ionization energy of the hydrogen atom (Z=1,n=1Z = 1, n = 1).

    For Li2+\text{Li}^{2+}, the atomic number is Z=3Z = 3.

    It is given that the energy of state S2\text{S}_2 is equal to the ground state energy of the hydrogen atom (−EH-E_H):
    −EH32n22=−EH-E_H \frac{3^2}{n_2^2} = -E_H

    Solving for n2n_2:
    9n22=1  ⟹  n22=9  ⟹  n2=3\frac{9}{n_2^2} = 1 \implies n_2^2 = 9 \implies n_2 = 3

  2. Radial Nodes of State S2\text{S}_2:
    The number of radial nodes for an orbital is given by the formula:
    Radial nodes=n−l−1\text{Radial nodes} = n - l - 1

    We are given that state S2\text{S}_2 has 11 radial node. Substituting n2=3n_2 = 3:
    1=3−l−11 = 3 - l - 1
    1=2−l  ⟹  l=11 = 2 - l \implies l = 1

Thus, the orbital angular momentum quantum number of state S2\text{S}_2 is l=1l = 1.

Correct Option: B