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Moles of Benzene Formed from Reduction of Phenol with Zinc

4.7 g4.7\text{ g} of phenol is heated with Zn\text{Zn} to give product X\text{X}. If this reaction goes to 60%60\% completion then the number of moles of compound X\text{X} formed will be _____ ×102\times 10^{-2}. (Nearest Integer) (Given molar mass in g mol1:H:1,C:12,O:16\text{g mol}^{-1} : \text{H}: 1, \text{C}: 12, \text{O}: 16)

Official Numerical Answer3

Step-by-Step Solution

When phenol (C6H5OH\text{C}_6\text{H}_5\text{OH}) is heated with zinc (Zn\text{Zn}) dust, it undergoes reduction to form benzene (C6H6\text{C}_6\text{H}_6), which is product X\text{X}, along with zinc oxide (ZnO\text{ZnO}).

The balanced chemical equation for the reduction reaction is: C6H5OH+ZnΔC6H6+ZnO\text{C}_6\text{H}_5\text{OH} + \text{Zn} \xrightarrow{\Delta} \text{C}_6\text{H}_6 + \text{ZnO}

Step 1: Calculate the molar mass of phenol (C6H5OH\text{C}_6\text{H}_5\text{OH}): Molar mass of phenol=(6×12)+(6×1)+16=72+6+16=94 g mol1\text{Molar mass of phenol} = (6 \times 12) + (6 \times 1) + 16 = 72 + 6 + 16 = 94 \text{ g mol}^{-1}

Step 2: Calculate the initial number of moles of phenol: Initial moles of phenol (nphenol)=Given massMolar mass=4.7 g94 g mol1=0.05 mol\text{Initial moles of phenol } (n_{\text{phenol}}) = \frac{\text{Given mass}}{\text{Molar mass}} = \frac{4.7 \text{ g}}{94 \text{ g mol}^{-1}} = 0.05 \text{ mol}

Step 3: Calculate the moles of benzene (X\text{X}) formed based on reaction completion: Given that the reaction goes to 60%60\% completion, the number of moles of phenol converted into product X\text{X} is: nreacted=0.05 mol×60100=0.03 moln_{\text{reacted}} = 0.05 \text{ mol} \times \frac{60}{100} = 0.03 \text{ mol}

From the stoichiometry of the reaction, 1 mole1 \text{ mole} of phenol gives 1 mole1 \text{ mole} of benzene (X\text{X}). Therefore, the number of moles of product X\text{X} formed is: nX=0.03 mol=3×102 moln_{\text{X}} = 0.03 \text{ mol} = 3 \times 10^{-2} \text{ mol}

Thus, the required value is 3.

Moles of Benzene Formed from Reduction of Phenol with Zinc | Chemistry PYQ Solution - JEE Challenger