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Identify Amino Acid Giving Violet Color with Ferric Chloride

Which of the following amino acid will give violet coloured complex with neutral ferric chloride solution ?

Options

A

Threonine

B

Serine

C

Tyrosine

Correct
D

Cysteine

Topics & Concepts

Step-by-Step Solution

To determine which amino acid gives a violet-coloured complex with neutral ferric chloride (FeCl3\text{FeCl}_3) solution, we examine the functional groups present in each amino acid:

  1. Neutral Ferric Chloride Test: Neutral FeCl3\text{FeCl}_3 solution is a specific test for the presence of a phenolic hydroxyl group (C6H4OH-\text{C}_6\text{H}_4\text{OH}). Compounds containing a phenolic OH-\text{OH} group react with Fe3+\text{Fe}^{3+} ions to form a characteristic colored coordination complex (often violet, blue, or green): 6Ar-OH+Fe3+[Fe(OAr)6]3+6H+6\text{Ar-OH} + \text{Fe}^{3+} \rightarrow [\text{Fe}(\text{OAr})_6]^{3-} + 6\text{H}^+

  2. Analysis of the Options:

    • Threonine: Contains an aliphatic hydroxyl group (CH(OH)CH3-\text{CH}(\text{OH})\text{CH}_3). Aliphatic alcohols do not give a positive neutral FeCl3\text{FeCl}_3 test.
    • Serine: Contains an aliphatic hydroxyl group (CH2OH-\text{CH}_2\text{OH}). Aliphatic alcohols do not react with FeCl3\text{FeCl}_3 to give a violet color.
    • Tyrosine: Contains a phenolic hydroxyl group (a hydroxyphenyl side chain, CH2-C6H4-OH-\text{CH}_2\text{-C}_6\text{H}_4\text{-OH}). Owing to this phenolic group, it reacts with neutral FeCl3\text{FeCl}_3 solution to yield a violet-coloured complex.
    • Cysteine: Contains a thiol group (CH2SH-\text{CH}_2\text{SH}), which does not form a violet phenolic complex with neutral FeCl3\text{FeCl}_3.

Thus, Tyrosine is the only amino acid among the given choices that reacts with neutral ferric chloride solution to give a violet-coloured complex.

Correct Option: C (Tyrosine)

Identify Amino Acid Giving Violet Color with Ferric Chloride | Chemistry PYQ Solution - JEE Challenger