Identification of Compound N in Metal Displacement Reaction
When a metal rod is dipped into an aqueous colourless concentrated solution of compound , the solution turns light blue. Addition of aqueous to the blue solution gives a white precipitate . Addition of aqueous dissolves and gives an intense blue solution.
The compound is
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Topics & Concepts
Step-by-Step Solution
To determine the identity of compound , let us analyze the step-by-step chemical transformations described in the passage:
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Reaction of Metal with Compound :
When the metal rod is dipped into a colourless aqueous solution of compound , the solution turns light blue. The light blue colour of the aqueous solution indicates the formation of copper(II) ions, , which means metal is Copper ().For copper to displace the metal ion from compound , the metal ion must have a higher reduction potential than (). Among the options, silver ion () has a standard reduction potential of . Thus, copper reduces to silver metal while itself oxidising to :
Therefore, compound is silver nitrate, . -
Precipitation with :
When aqueous is added to the resulting blue solution containing unreacted ions, a white precipitate of silver chloride () is formed:
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Dissolution and Complex Formation with :
Addition of aqueous ammonia () dissolves the white precipitate () by forming the soluble diamminesilver(I) complex ion:
Simultaneously, the excess ammonia reacts with the ions present in the solution to form the tetraamminecopper(II) complex, which gives an intense deep-blue solution:
Thus, the compound is .
Correct Option: A