JEE Challenger
More from Coordination Compounds

Identification of Compound N in Metal Displacement Reaction

Comprehension Passage

When a metal rod M\mathbf{M} is dipped into an aqueous colourless concentrated solution of compound N\mathbf{N}, the solution turns light blue. Addition of aqueous NaCl\text{NaCl} to the blue solution gives a white precipitate O\mathbf{O}. Addition of aqueous NH3\text{NH}_3 dissolves O\mathbf{O} and gives an intense blue solution.

The compound N\mathbf{N} is

Options

A

AgNO3\text{AgNO}_3

Correct
B

Zn(NO3)2\text{Zn(NO}_3)_2

C

Al(NO3)3\text{Al(NO}_3)_3

D

Pb(NO3)2\text{Pb(NO}_3)_2

Step-by-Step Solution

To determine the identity of compound N\mathbf{N}, let us analyze the step-by-step chemical transformations described in the passage:

  1. Reaction of Metal M\mathbf{M} with Compound N\mathbf{N}:
    When the metal rod M\mathbf{M} is dipped into a colourless aqueous solution of compound N\mathbf{N}, the solution turns light blue. The light blue colour of the aqueous solution indicates the formation of copper(II) ions, Cu2+(aq)\text{Cu}^{2+}(\text{aq}), which means metal M\mathbf{M} is Copper (Cu\text{Cu}).

    For copper to displace the metal ion from compound N\mathbf{N}, the metal ion must have a higher reduction potential than Cu2+/Cu\text{Cu}^{2+}/\text{Cu} (E∘=+0.34 VE^\circ = +0.34\text{ V}). Among the options, silver ion (Ag+\text{Ag}^+) has a standard reduction potential of EAg+/Ag∘=+0.80 VE^\circ_{\text{Ag}^+/\text{Ag}} = +0.80\text{ V}. Thus, copper reduces Ag+\text{Ag}^+ to silver metal while itself oxidising to Cu2+\text{Cu}^{2+}:
    Cu(s)+2AgNO3(aq)→Cu(NO3)2(aq)+2Ag(s)\text{Cu}(s) + 2\text{AgNO}_3(\text{aq}) \rightarrow \text{Cu(NO}_3)_2(\text{aq}) + 2\text{Ag}(s)
    Therefore, compound N\mathbf{N} is silver nitrate, AgNO3\text{AgNO}_3.

  2. Precipitation with NaCl\text{NaCl}:
    When aqueous NaCl\text{NaCl} is added to the resulting blue solution containing unreacted Ag+\text{Ag}^+ ions, a white precipitate O\mathbf{O} of silver chloride (AgCl\text{AgCl}) is formed:
    Ag+(aq)+Cl−(aq)→AgCl(s)(white precipitate O)\text{Ag}^+(\text{aq}) + \text{Cl}^-(\text{aq}) \rightarrow \text{AgCl}(s) \quad (\text{white precipitate } \mathbf{O})

  3. Dissolution and Complex Formation with NH3\text{NH}_3:
    Addition of aqueous ammonia (NH3\text{NH}_3) dissolves the white precipitate O\mathbf{O} (AgCl\text{AgCl}) by forming the soluble diamminesilver(I) complex ion:
    AgCl(s)+2NH3(aq)→[Ag(NH3)2]+(aq)+Cl−(aq)\text{AgCl}(s) + 2\text{NH}_3(\text{aq}) \rightarrow [\text{Ag(NH}_3)_2]^+(\text{aq}) + \text{Cl}^-(\text{aq})

    Simultaneously, the excess ammonia reacts with the Cu2+\text{Cu}^{2+} ions present in the solution to form the tetraamminecopper(II) complex, which gives an intense deep-blue solution:
    Cu2+(aq)+4NH3(aq)→[Cu(NH3)4]2+(aq)(intense blue solution)\text{Cu}^{2+}(\text{aq}) + 4\text{NH}_3(\text{aq}) \rightarrow [\text{Cu(NH}_3)_4]^{2+}(\text{aq}) \quad (\text{intense blue solution})

Thus, the compound N\mathbf{N} is AgNO3\text{AgNO}_3.

Correct Option: A