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Heat Exchange and Equilibrium Calculation for Melting Ice

A piece of ice (heat capacity =2100 J kg−1 ∘C−1= 2100\text{ J kg}^{-1}\text{ }^\circ\text{C}^{-1} and latent heat =3.36×105 J kg−1= 3.36 \times 10^5\text{ J kg}^{-1}) of mass m\text{m} grams is at −5∘C-5^\circ\text{C} at atmospheric pressure. It is given 420 J420\text{ J} of heat so that the ice starts melting. Finally when the ice-water mixture is in equilibrium, it is found that 1 gm1\text{ gm} of ice has melted. Assuming there is no other heat exchange in the process, the value of m\text{m} is

Official Numerical Answer8

Step-by-Step Solution

To find the initial mass of the ice piece, mm (in grams), we analyze the two stages in which the supplied heat is absorbed:

  1. Heating the entire mass of ice from −5∘C-5^\circ\text{C} to 0∘C0^\circ\text{C}:
    The heat required to raise the temperature of m gramsm\text{ grams} (which is m×10−3 kgm \times 10^{-3}\text{ kg}) of ice is given by:
    Q1=Mice⋅cice⋅ΔTQ_1 = M_{\text{ice}} \cdot c_{\text{ice}} \cdot \Delta T
    Q1=(m×10−3 kg)×(2100 J kg−1 ∘C−1)×(0−(−5))∘CQ_1 = (m \times 10^{-3}\text{ kg}) \times (2100\text{ J kg}^{-1}\text{ }^\circ\text{C}^{-1}) \times (0 - (-5))^\circ\text{C}
    Q1=m×10−3×2100×5=10.5m JQ_1 = m \times 10^{-3} \times 2100 \times 5 = 10.5 m\text{ J}

  2. Melting 1 gm1\text{ gm} of ice at 0∘C0^\circ\text{C}:
    The mass of the ice melted is mmelted=1 gm=10−3 kgm_{\text{melted}} = 1\text{ gm} = 10^{-3}\text{ kg}. The heat required for melting this mass is:
    Q2=mmelted⋅LfQ_2 = m_{\text{melted}} \cdot L_f
    Q2=(10−3 kg)×(3.36×105 J kg−1)=336 JQ_2 = (10^{-3}\text{ kg}) \times (3.36 \times 10^5\text{ J kg}^{-1}) = 336\text{ J}

  3. Total heat supplied to the system:
    Since there is no other heat exchange, the total heat supplied Q=420 JQ = 420\text{ J} is the sum of Q1Q_1 and Q2Q_2:
    Q=Q1+Q2Q = Q_1 + Q_2
    420=10.5m+336420 = 10.5 m + 336
    10.5m=420−33610.5 m = 420 - 336
    10.5m=8410.5 m = 84
    m=8410.5=8m = \frac{84}{10.5} = 8

Thus, the value of mm is 8.