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Fraction of Radioisotope Nuclei Decayed in Given Time Duration

A freshly prepared radioactive isotope sample having a half-life of 1386 s1386\text{ s} exhibits an initial activity of 10310^3 disintegrations per second. Taking ln⁡2=0.693\ln 2 = 0.693, compute the percentage of the initial quantity of nuclei that will undergo decay in the first 80 s80\text{ s} (rounded off to the nearest integer).

Official Numerical Answer4

Topics & Concepts

Step-by-Step Solution

To find the percentage of the initial quantity of nuclei that undergo radioactive decay in the first t=80 st = 80\text{ s}, we follow these steps:

1. Determine the decay constant (λ\lambda): The relationship between the half-life (T1/2T_{1/2}) and the decay constant (λ\lambda) is given by: λ=ln⁡2T1/2\lambda = \frac{\ln 2}{T_{1/2}}

Given:

  • T1/2=1386 sT_{1/2} = 1386\text{ s}
  • ln⁡2=0.693\ln 2 = 0.693

Substituting the given values: λ=0.6931386 s−1=693×10−31386 s−1=0.5×10−3 s−1=5×10−4 s−1\lambda = \frac{0.693}{1386}\text{ s}^{-1} = \frac{693 \times 10^{-3}}{1386}\text{ s}^{-1} = 0.5 \times 10^{-3}\text{ s}^{-1} = 5 \times 10^{-4}\text{ s}^{-1}

2. Calculate the exponent λt\lambda t: For t=80 st = 80\text{ s}: λt=(5×10−4 s−1)×80 s=400×10−4=0.04\lambda t = \left(5 \times 10^{-4}\text{ s}^{-1}\right) \times 80\text{ s} = 400 \times 10^{-4} = 0.04

3. Calculate the fraction of nuclei that decay: The number of nuclei remaining at time tt is: N(t)=N0e−λtN(t) = N_0 e^{-\lambda t}

The number of nuclei that undergo decay in time tt is: ΔN=N0−N(t)=N0(1−e−λt)\Delta N = N_0 - N(t) = N_0 \left(1 - e^{-\lambda t}\right)

Thus, the fraction of nuclei decayed is: ΔNN0=1−e−λt\frac{\Delta N}{N_0} = 1 - e^{-\lambda t}

Since λt=0.04≪1\lambda t = 0.04 \ll 1, we can use the Taylor series expansion e−x≈1−xe^{-x} \approx 1 - x: ΔNN0≈1−(1−λt)=λt=0.04\frac{\Delta N}{N_0} \approx 1 - (1 - \lambda t) = \lambda t = 0.04

4. Compute the percentage: Percentage decayed=ΔNN0×100%=0.04×100%=4%\text{Percentage decayed} = \frac{\Delta N}{N_0} \times 100\% = 0.04 \times 100\% = 4\%

(Taking the exact value: 1−e−0.04≈0.03921 - e^{-0.04} \approx 0.0392, which yields 3.92%3.92\%, rounding off to the nearest integer gives 44.)

Answer: 4