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Find Temperature of Mixture of Two Ideal Gases

One gas of n1n_1 mole of molecules at temperature T1T_1, volume V1V_1, and pressure P1P_1, and another gas of n2n_2 mole of molecules at temperature T2T_2, volume V2V_2, and pressure P2P_2, are mixed resulting in pressure PP and volume VV of the mixture. The temperature of the mixture is ________.

Options

A

(T1+T2)/2(T_1 + T_2)/2

B

T1T2PV/(T2P1V1+T1P2V2)T_1 T_2 PV/(T_2 P_1 V_1 + T_1 P_2 V_2)

Correct
C

(T2P1V1+T1P2V2)/(T1T2PV)(T_2 P_1 V_1 + T_1 P_2 V_2)/(T_1 T_2 PV)

D

T1T2/2|T_1 - T_2|/2

Topics & Concepts

Step-by-Step Solution

To find the temperature TT of the mixture of two ideal gases, we use the ideal gas equation PV=nRTPV = nRT.

For the first gas: P1V1=n1RT1    n1=P1V1RT1P_1 V_1 = n_1 R T_1 \implies n_1 = \frac{P_1 V_1}{R T_1}

For the second gas: P2V2=n2RT2    n2=P2V2RT2P_2 V_2 = n_2 R T_2 \implies n_2 = \frac{P_2 V_2}{R T_2}

When the two gases are mixed, the total number of moles nn in the mixture is the sum of the individual moles: n=n1+n2n = n_1 + n_2

For the resulting mixture with pressure PP, volume VV, and temperature TT: PV=nRTP V = n R T

Substituting n=n1+n2n = n_1 + n_2 into the equation for the mixture: PV=(n1+n2)RTP V = (n_1 + n_2) R T

Now, substitute the expressions for n1n_1 and n2n_2: PV=(P1V1RT1+P2V2RT2)RTP V = \left( \frac{P_1 V_1}{R T_1} + \frac{P_2 V_2}{R T_2} \right) R T

Canceling the universal gas constant RR: PV=(P1V1T1+P2V2T2)TP V = \left( \frac{P_1 V_1}{T_1} + \frac{P_2 V_2}{T_2} \right) T

Taking a common denominator for the terms inside the parentheses: PV=(T2P1V1+T1P2V2T1T2)TP V = \left( \frac{T_2 P_1 V_1 + T_1 P_2 V_2}{T_1 T_2} \right) T

Solving for the temperature TT of the mixture: T=T1T2PVT2P1V1+T1P2V2T = \frac{T_1 T_2 P V}{T_2 P_1 V_1 + T_1 P_2 V_2}

Thus, the correct option is B.

Find Temperature of Mixture of Two Ideal Gases | Physics PYQ Solution - JEE Challenger