Evaluation of Statements on Maltose and Lactose Reducing Properties
Given below are two statements:
Statement I: The structure of Maltose is given below:
Maltose is a non-reducing sugar.
Statement II: The structure of Lactose is given below:
Lactose is a reducing sugar.
In the light of the above statements, choose the correct answer from the options given below


Options
A
Both Statement I and Statement II are true
B
Both Statement I and Statement II are false
C
Statement I is true but Statement II is false
DCorrect
Statement I is false but Statement II is true
Topics & Concepts
Step-by-Step Solution
To determine the correctness of the given statements, let us analyze the chemical properties and structures of Maltose and Lactose:
-
Analysis of Statement I:
- Maltose is a disaccharide formed by the condensation of two -D-glucose molecules linked via an glycosidic bond.
- The C-1 (anomeric carbon) of the second glucose unit possesses a free hemiacetal group (), which can exist in equilibrium with an open-chain aldehyde form.
- Because of this free aldehyde group, maltose exhibits mutarotation and reduces Fehling's solution and Tollen's reagent. Therefore, Maltose is a reducing sugar.
- Thus, Statement I ("Maltose is a non-reducing sugar") is false.
-
Analysis of Statement II:
- Lactose is a disaccharide composed of -D-galactose and -D-glucose linked by a glycosidic linkage.
- The C-1 (anomeric carbon) of the glucose unit is free and present as a hemiacetal group.
- Since it can open to yield a free aldehyde group, lactose easily reduces Fehling's and Tollen's reagents. Therefore, Lactose is a reducing sugar.
- Thus, Statement II ("Lactose is a reducing sugar") is true.
Conclusion: Statement I is false but Statement II is true.
Correct Option: D