Electronegativity Order and Oxidation State of Oxygen
Given below are two statements:
Statement I: The correct order of electronegativity of fluorine, oxygen and nitrogen is .
Statement II: The oxidation state of oxygen in is and in is .
In the light of the above statements, choose the correct answer from the options given below
Options
Both Statement I and Statement II are true
Both Statement I and Statement II are false
Statement I is true but Statement II is false
Statement I is false but Statement II is true
Step-by-Step Solution
To determine the correctness of the given statements, let us analyze them individually:
Analysis of Statement I: Electronegativity increases across a period from left to right in the periodic table due to an increase in nuclear charge and a decrease in atomic radius.
Nitrogen (), Oxygen (), and Fluorine () belong to Period 2 of the periodic table. Their electronegativity values on the Pauling scale are approximately:
Thus, the correct trend of electronegativity is:
Therefore, Statement I is true.
Analysis of Statement II:
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In oxygen difluoride (): Since fluorine is more electronegative than oxygen, each fluorine atom is assigned an oxidation state of . Let be the oxidation state of oxygen: Hence, the oxidation state of oxygen in is .
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In sodium oxide (): Sodium () is an alkali metal and always exhibits an oxidation state of in its compounds. Let be the oxidation state of oxygen: Hence, the oxidation state of oxygen in is .
Therefore, Statement II is true.
Conclusion: Since both Statement I and Statement II are true, the correct answer is option A.