JEE Challenger
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Electronegativity Order and Oxidation State of Oxygen

Given below are two statements:

Statement I: The correct order of electronegativity of fluorine, oxygen and nitrogen is F>O>N\text{F} > \text{O} > \text{N}.

Statement II: The oxidation state of oxygen in OF2\text{OF}_2 is +2+2 and in Na2O\text{Na}_2\text{O} is 2-2.

In the light of the above statements, choose the correct answer from the options given below

Options

A

Both Statement I and Statement II are true

Correct
B

Both Statement I and Statement II are false

C

Statement I is true but Statement II is false

D

Statement I is false but Statement II is true

Step-by-Step Solution

To determine the correctness of the given statements, let us analyze them individually:

Analysis of Statement I: Electronegativity increases across a period from left to right in the periodic table due to an increase in nuclear charge and a decrease in atomic radius.

Nitrogen (N\text{N}), Oxygen (O\text{O}), and Fluorine (F\text{F}) belong to Period 2 of the periodic table. Their electronegativity values on the Pauling scale are approximately:

  • F=4.0\text{F} = 4.0
  • O=3.5\text{O} = 3.5
  • N=3.0\text{N} = 3.0

Thus, the correct trend of electronegativity is: F>O>N\text{F} > \text{O} > \text{N}

Therefore, Statement I is true.


Analysis of Statement II:

  1. In oxygen difluoride (OF2\text{OF}_2): Since fluorine is more electronegative than oxygen, each fluorine atom is assigned an oxidation state of 1-1. Let xx be the oxidation state of oxygen: x+2(1)=0    x=+2x + 2(-1) = 0 \implies x = +2 Hence, the oxidation state of oxygen in OF2\text{OF}_2 is +2+2.

  2. In sodium oxide (Na2O\text{Na}_2\text{O}): Sodium (Na\text{Na}) is an alkali metal and always exhibits an oxidation state of +1+1 in its compounds. Let yy be the oxidation state of oxygen: 2(+1)+y=0    y=22(+1) + y = 0 \implies y = -2 Hence, the oxidation state of oxygen in Na2O\text{Na}_2\text{O} is 2-2.

Therefore, Statement II is true.


Conclusion: Since both Statement I and Statement II are true, the correct answer is option A.

Electronegativity Order and Oxidation State of Oxygen | Chemistry PYQ Solution - JEE Challenger