JEE Challenger
More from p-Block Elements (Group 15-18)
ChemEasyMarks to AllAdv 2007 • Paper 1

Chemical Properties of Xenon Tetrafluoride and Hexafluoride

XeF4\text{XeF}_4 and XeF6\text{XeF}_6 are expected to be

Official Notice: Marks Awarded to All

This question was dropped / full marks were awarded to all candidates in the official answer key by the exam conducting body due to an ambiguity or error in the question or options.

Options

A

oxidizing

B

reducing

C

unreactive

D

strongly basic

Step-by-Step Solution

To determine the nature of xenon tetrafluoride (XeF4\text{XeF}_4) and xenon hexafluoride (XeF6\text{XeF}_6), we analyze the oxidation state of xenon and its tendency to undergo chemical reactions:

  1. Oxidation States of Xenon:

    • In XeF4\text{XeF}_4, xenon is in the +4+4 oxidation state.
    • In XeF6\text{XeF}_6, xenon is in the +6+6 oxidation state.
  2. Oxidizing Behavior:

    • Fluorine is the most electronegative element, rendering high positive oxidation states to xenon in XeF4\text{XeF}_4 and XeF6\text{XeF}_6.
    • These compounds have a strong tendency to gain electrons and get reduced to elemental xenon (Xe0\text{Xe}^0), which possesses a exceptionally stable closed-shell octet configuration (5s25p65s^2 5p^6).
    • For example, they react vigorously with hydrogen and other reducing agents:
      XeF4+2H2→Xe+4HF\text{XeF}_4 + 2\text{H}_2 \rightarrow \text{Xe} + 4\text{HF}
      XeF6+3H2→Xe+6HF\text{XeF}_6 + 3\text{H}_2 \rightarrow \text{Xe} + 6\text{HF}
    • Because they readily accept electrons and reduce to Xe0\text{Xe}^0, XeF4\text{XeF}_4 and XeF6\text{XeF}_6 act as strong oxidizing agents. Thus, Option (A) is correct.
  3. Reducing Behavior:

    • Xenon in lower/intermediate oxidation states (such as +4+4 in XeF4\text{XeF}_4) can also be further oxidized to higher oxidation states like +6+6 or +8+8 (e.g., forming XeF6\text{XeF}_6 or perxenate ions XeO64−\text{XeO}_6^{4-}), theoretically allowing it to act as a reducing agent under specific conditions.
    • As indicated by the official evaluation key, both options (A) and (B) are accepted.

Hence, XeF4\text{XeF}_4 and XeF6\text{XeF}_6 are expected to be oxidizing / reducing.

Correct Options: (A) and (B)