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Calculate Mass of Iron Converted into Fe3O4 by Steam

The mass of iron converted into Fe3O4\text{Fe}_3\text{O}_4 by the action of 18 g18\text{ g} of steam is : (Given : Molar mass of H\text{H}, O\text{O} and Fe\text{Fe} are 11, 1616 and 56 g mol156\text{ g mol}^{-1} respectively) Assume iron is present in excess :

Options

A

2.1 g2.1\text{ g}

B

4.2 g4.2\text{ g}

C

21 g21\text{ g}

D

42 g42\text{ g}

Correct

Step-by-Step Solution

To find the mass of iron (Fe\text{Fe}) converted into magnetic iron oxide (Fe3O4\text{Fe}_3\text{O}_4), we start by writing the balanced chemical reaction between iron and steam (H2O\text{H}_2\text{O}):

3Fe(s)+4H2O(g)Fe3O4(s)+4H2(g)3\text{Fe}(s) + 4\text{H}_2\text{O}(g) \rightarrow \text{Fe}_3\text{O}_4(s) + 4\text{H}_2(g)

Step 1: Calculate the molar masses of the substances.

  • Molar mass of steam (H2O\text{H}_2\text{O}) = 2(1)+16=18 g mol12(1) + 16 = 18\text{ g mol}^{-1}
  • Molar mass of iron (Fe\text{Fe}) = 56 g mol156\text{ g mol}^{-1}

Step 2: Calculate the number of moles of steam available. Moles of H2O=Given massMolar mass=18 g18 g mol1=1 mol\text{Moles of }\text{H}_2\text{O} = \frac{\text{Given mass}}{\text{Molar mass}} = \frac{18\text{ g}}{18\text{ g mol}^{-1}} = 1\text{ mol}

Step 3: Determine the required moles of iron using stoichiometry. From the balanced chemical equation, 4 moles4\text{ moles} of H2O\text{H}_2\text{O} react completely with 3 moles3\text{ moles} of Fe\text{Fe}.

Therefore, 1 mole1\text{ mole} of H2O\text{H}_2\text{O} will react with: Moles of Fe=34×1 mol=0.75 mol\text{Moles of }\text{Fe} = \frac{3}{4} \times 1\text{ mol} = 0.75\text{ mol}

Step 4: Calculate the mass of iron consumed. Mass of Fe=Moles of Fe×Molar mass of Fe\text{Mass of }\text{Fe} = \text{Moles of }\text{Fe} \times \text{Molar mass of }\text{Fe} Mass of Fe=0.75 mol×56 g mol1=42 g\text{Mass of }\text{Fe} = 0.75\text{ mol} \times 56\text{ g mol}^{-1} = 42\text{ g}

Thus, the mass of iron converted into Fe3O4\text{Fe}_3\text{O}_4 is 42 g42\text{ g}.

Correct Option: D

Calculate Mass of Iron Converted into Fe3O4 by Steam | Chemistry PYQ Solution - JEE Challenger