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Calculate Density of Metal in CCP Lattice

The density (in g cm3\text{g cm}^{-3}) of the metal which forms a cubic close packed (ccp) lattice with an axial distance (edge length) equal to 400 pm400\text{ pm} is ______.

Use: Atomic mass of metal =105.6 amu= 105.6\text{ amu} and Avogadro's constant =6×1023 mol1= 6 \times 10^{23}\text{ mol}^{-1}

Official Numerical Answer10.85 to 11.1

Topics & Concepts

Step-by-Step Solution

To calculate the density of the metal, we use the standard unit cell density formula:

ρ=Z×Ma3×NA\rho = \frac{Z \times M}{a^3 \times N_A}

where:

  • ZZ is the number of atoms per unit cell. For a cubic close packed (ccp) or face-centered cubic (fcc) lattice, Z=4Z = 4.
  • MM is the atomic mass of the metal =105.6 g mol1= 105.6 \text{ g mol}^{-1}.
  • aa is the edge length of the unit cell =400 pm=400×1010 cm=4×108 cm= 400 \text{ pm} = 400 \times 10^{-10} \text{ cm} = 4 \times 10^{-8} \text{ cm}.
  • NAN_A is Avogadro's constant =6×1023 mol1= 6 \times 10^{23} \text{ mol}^{-1}.

Step-by-Step Calculation:

  1. Volume of the unit cell (V=a3V = a^3): V=(4×108 cm)3=64×1024 cm3V = (4 \times 10^{-8} \text{ cm})^3 = 64 \times 10^{-24} \text{ cm}^3

  2. Substitute the given values into the density equation: ρ=4×105.6 g mol1(64×1024 cm3)×(6×1023 mol1)\rho = \frac{4 \times 105.6 \text{ g mol}^{-1}}{(64 \times 10^{-24} \text{ cm}^3) \times (6 \times 10^{23} \text{ mol}^{-1})}

  3. Simplify the denominator: Denominator=64×6×101=384×101=38.4 cm3 mol1\text{Denominator} = 64 \times 6 \times 10^{-1} = 384 \times 10^{-1} = 38.4 \text{ cm}^3 \text{ mol}^{-1}

  4. Calculate the density (ρ\rho): ρ=422.438.4=11 g cm3\rho = \frac{422.4}{38.4} = 11 \text{ g cm}^{-3}

The density of the metal is 11 (or 11.00).

Calculate Density of Metal in CCP Lattice | Chemistry PYQ Solution - JEE Challenger